Synthesis and characterization of a new polypyrrole based on N-vinyl pyrrole

Wanqin Wang; Demei Yu; Feng Tian

doi:10.1016/j.synthmet.2008.04.016

Synthesis and characterization of a new polypyrrole based on N-vinyl pyrrole

Wanqin Wang
, Demei Yu
, Feng Tian

Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

A novel polymer constituted of N-substituted pyrrole was synthesized by chemical oxidative polymerization from N-vinylpyrrole monomer. The structure of the resulting polymer was characterized by FT-IR, ¹H NMR and element analysis. The results indicated that the polymer was comprised of two chains, i.e. α-coupled polypyrrole and polyethylene, and the two chains were found to have the same average degree of polymerization. The investigation of the solubility showed that the polymer was soluble in common organic solvents and could be cast into thin films from a chloroform solution. Interestingly, the polymer displayed strong optical absorption in the visible region and exhibited photoluminescence as determined by UV-vis and fluorescence spectrum analysis.

Original language	English
Pages (from-to)	717-721
Number of pages	5
Journal	Synthetic Metals
Volume	158
Issue number	17-18
DOIs	https://doi.org/10.1016/j.synthmet.2008.04.016
State	Published - Oct 2008

Keywords

N-Vinylpyrrole
Polypyrrole
Synthesis

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10.1016/j.synthmet.2008.04.016

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title = "Synthesis and characterization of a new polypyrrole based on N-vinyl pyrrole",

abstract = "A novel polymer constituted of N-substituted pyrrole was synthesized by chemical oxidative polymerization from N-vinylpyrrole monomer. The structure of the resulting polymer was characterized by FT-IR, 1H NMR and element analysis. The results indicated that the polymer was comprised of two chains, i.e. α-coupled polypyrrole and polyethylene, and the two chains were found to have the same average degree of polymerization. The investigation of the solubility showed that the polymer was soluble in common organic solvents and could be cast into thin films from a chloroform solution. Interestingly, the polymer displayed strong optical absorption in the visible region and exhibited photoluminescence as determined by UV-vis and fluorescence spectrum analysis.",

keywords = "N-Vinylpyrrole, Polypyrrole, Synthesis",

author = "Wanqin Wang and Demei Yu and Feng Tian",

year = "2008",

month = oct,

doi = "10.1016/j.synthmet.2008.04.016",

language = "英语",

volume = "158",

pages = "717--721",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis and characterization of a new polypyrrole based on N-vinyl pyrrole

AU - Wang, Wanqin

AU - Yu, Demei

AU - Tian, Feng

PY - 2008/10

Y1 - 2008/10

N2 - A novel polymer constituted of N-substituted pyrrole was synthesized by chemical oxidative polymerization from N-vinylpyrrole monomer. The structure of the resulting polymer was characterized by FT-IR, 1H NMR and element analysis. The results indicated that the polymer was comprised of two chains, i.e. α-coupled polypyrrole and polyethylene, and the two chains were found to have the same average degree of polymerization. The investigation of the solubility showed that the polymer was soluble in common organic solvents and could be cast into thin films from a chloroform solution. Interestingly, the polymer displayed strong optical absorption in the visible region and exhibited photoluminescence as determined by UV-vis and fluorescence spectrum analysis.

AB - A novel polymer constituted of N-substituted pyrrole was synthesized by chemical oxidative polymerization from N-vinylpyrrole monomer. The structure of the resulting polymer was characterized by FT-IR, 1H NMR and element analysis. The results indicated that the polymer was comprised of two chains, i.e. α-coupled polypyrrole and polyethylene, and the two chains were found to have the same average degree of polymerization. The investigation of the solubility showed that the polymer was soluble in common organic solvents and could be cast into thin films from a chloroform solution. Interestingly, the polymer displayed strong optical absorption in the visible region and exhibited photoluminescence as determined by UV-vis and fluorescence spectrum analysis.

KW - N-Vinylpyrrole

KW - Polypyrrole

KW - Synthesis

UR - https://www.scopus.com/pages/publications/52049112093

U2 - 10.1016/j.synthmet.2008.04.016

DO - 10.1016/j.synthmet.2008.04.016

M3 - 文章

AN - SCOPUS:52049112093

SN - 0379-6779

VL - 158

SP - 717

EP - 721

JO - Synthetic Metals

JF - Synthetic Metals

IS - 17-18

ER -

Synthesis and characterization of a new polypyrrole based on N-vinyl pyrrole

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Keywords

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