Surface-silvered polyimide films prepared by plasma-induced grafting of viologen and electroless plating

Weisong Cui; Dezhen Wu; Wen Cai Wang; Liqun Zhang; Bing Cao; Riguang Jin

doi:10.1016/j.surfcoat.2009.01.018

Surface-silvered polyimide films prepared by plasma-induced grafting of viologen and electroless plating

Weisong Cui
, Dezhen Wu
, Wen Cai Wang
, Liqun Zhang
, Bing Cao
, Riguang Jin

Beijing University of Chemical Technology

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A vinyl-containing viologen, 1,1'-bis(4-vinylbenzyl)-4,4'-bipyridinium dinitrate (VBVN), was synthesized and subsequently graft-copolymerized on argon plasma-pretreated polyimide (PI) films. Silver nanoparticles can be deposited on the surface of the PI grafted with VBVN film through photo-induced reduction of the silver ions in salt solution. The surface compositions of the modified PI films were studied by X-ray photoelectron spectroscopy (XPS). The topography of the electroless deposited PI films was characterized by SEM and AFM. The results show that the silver nanoparticles are uniformly distributed on the surface of PI films, and the size and distribution of the nanoparticles can be varied by changing the UV irradiation time.

Original language	English
Pages (from-to)	1885-1890
Number of pages	6
Journal	Surface and Coatings Technology
Volume	203
Issue number	13
DOIs	https://doi.org/10.1016/j.surfcoat.2009.01.018
State	Published - 25 Mar 2009
Externally published	Yes

Keywords

Electroless plating
Graft copolymerization
Polyimides
Silver
Viologen

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10.1016/j.surfcoat.2009.01.018

Cite this

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title = "Surface-silvered polyimide films prepared by plasma-induced grafting of viologen and electroless plating",

abstract = "A vinyl-containing viologen, 1,1'-bis(4-vinylbenzyl)-4,4'-bipyridinium dinitrate (VBVN), was synthesized and subsequently graft-copolymerized on argon plasma-pretreated polyimide (PI) films. Silver nanoparticles can be deposited on the surface of the PI grafted with VBVN film through photo-induced reduction of the silver ions in salt solution. The surface compositions of the modified PI films were studied by X-ray photoelectron spectroscopy (XPS). The topography of the electroless deposited PI films was characterized by SEM and AFM. The results show that the silver nanoparticles are uniformly distributed on the surface of PI films, and the size and distribution of the nanoparticles can be varied by changing the UV irradiation time.",

keywords = "Electroless plating, Graft copolymerization, Polyimides, Silver, Viologen",

author = "Weisong Cui and Dezhen Wu and Wang, \{Wen Cai\} and Liqun Zhang and Bing Cao and Riguang Jin",

year = "2009",

month = mar,

day = "25",

doi = "10.1016/j.surfcoat.2009.01.018",

language = "英语",

volume = "203",

pages = "1885--1890",

journal = "Surface and Coatings Technology",

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publisher = "Elsevier B.V.",

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}

TY - JOUR

T1 - Surface-silvered polyimide films prepared by plasma-induced grafting of viologen and electroless plating

AU - Cui, Weisong

AU - Wu, Dezhen

AU - Wang, Wen Cai

AU - Zhang, Liqun

AU - Cao, Bing

AU - Jin, Riguang

PY - 2009/3/25

Y1 - 2009/3/25

N2 - A vinyl-containing viologen, 1,1'-bis(4-vinylbenzyl)-4,4'-bipyridinium dinitrate (VBVN), was synthesized and subsequently graft-copolymerized on argon plasma-pretreated polyimide (PI) films. Silver nanoparticles can be deposited on the surface of the PI grafted with VBVN film through photo-induced reduction of the silver ions in salt solution. The surface compositions of the modified PI films were studied by X-ray photoelectron spectroscopy (XPS). The topography of the electroless deposited PI films was characterized by SEM and AFM. The results show that the silver nanoparticles are uniformly distributed on the surface of PI films, and the size and distribution of the nanoparticles can be varied by changing the UV irradiation time.

AB - A vinyl-containing viologen, 1,1'-bis(4-vinylbenzyl)-4,4'-bipyridinium dinitrate (VBVN), was synthesized and subsequently graft-copolymerized on argon plasma-pretreated polyimide (PI) films. Silver nanoparticles can be deposited on the surface of the PI grafted with VBVN film through photo-induced reduction of the silver ions in salt solution. The surface compositions of the modified PI films were studied by X-ray photoelectron spectroscopy (XPS). The topography of the electroless deposited PI films was characterized by SEM and AFM. The results show that the silver nanoparticles are uniformly distributed on the surface of PI films, and the size and distribution of the nanoparticles can be varied by changing the UV irradiation time.

KW - Electroless plating

KW - Graft copolymerization

KW - Polyimides

KW - Silver

KW - Viologen

UR - https://www.scopus.com/pages/publications/60949084700

U2 - 10.1016/j.surfcoat.2009.01.018

DO - 10.1016/j.surfcoat.2009.01.018

M3 - 文章

AN - SCOPUS:60949084700

SN - 0257-8972

VL - 203

SP - 1885

EP - 1890

JO - Surface and Coatings Technology

JF - Surface and Coatings Technology

IS - 13

ER -

Surface-silvered polyimide films prepared by plasma-induced grafting of viologen and electroless plating

Abstract

Keywords

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