Study of antiferroelectric PbZrO3-Pb(M1/2W 1/2)O3 (M = Mg, Zn & Mn) complex perovskite solid solutions

Z. Ren; N. Zhang; S. Huo; J. Y.Y. Wong; Z. G. Ye

doi:10.1080/00150193.2014.892409

Study of antiferroelectric PbZrO₃-Pb(M_1/2W _1/2)O₃ (M = Mg, Zn & Mn) complex perovskite solid solutions

Z. Ren
, N. Zhang
, S. Huo
, J. Y.Y. Wong
, Z. G. Ye

Faculty of Electronic and Information Engineering

Simon Fraser University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Ceramics of the perovskite solid solution of 0.99PbZrO₃-0. 01Pb(M_1/2W_1/2)O₃ (M = Mg, Zn&Mn) have been prepared by the solid state reaction method. Their crystal structures and dielectric and antiferroelectric properties have been characterized. It is found that the crystal structure of the solid solutions remains in the orthorhombic Pbam symmetry with the addition of Pb(M_1/2W_1/2)O ₃ up to 1 % while the induced polarization (P_Ind) is improved and the critical field (E_Cr) is decreased. The Curie temperature (T_C) is also decreased with the substitution of Pb(M _1/2W_1/2)O₃ for PbZrO₃ whereas the maximum permittivity (ε'max) is increased significantly. The grains of the ceramics are significantly grown, which could be attributed to the presence of a transient liquid phase in the solid solutions.

Original language	English
Pages (from-to)	27-34
Number of pages	8
Journal	Ferroelectrics
Volume	464
Issue number	1
DOIs	https://doi.org/10.1080/00150193.2014.892409
State	Published - 2014

Keywords

Antiferroelectric
Ceramics
Ferroelectric
Liquid phase sintering

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10.1080/00150193.2014.892409

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title = "Study of antiferroelectric PbZrO3-Pb(M1/2W 1/2)O3 (M = Mg, Zn \& Mn) complex perovskite solid solutions",

abstract = "Ceramics of the perovskite solid solution of 0.99PbZrO3-0. 01Pb(M1/2W1/2)O3 (M = Mg, Zn\&Mn) have been prepared by the solid state reaction method. Their crystal structures and dielectric and antiferroelectric properties have been characterized. It is found that the crystal structure of the solid solutions remains in the orthorhombic Pbam symmetry with the addition of Pb(M1/2W1/2)O 3 up to 1 \% while the induced polarization (PInd) is improved and the critical field (ECr) is decreased. The Curie temperature (TC) is also decreased with the substitution of Pb(M 1/2W1/2)O3 for PbZrO3 whereas the maximum permittivity (ε'max) is increased significantly. The grains of the ceramics are significantly grown, which could be attributed to the presence of a transient liquid phase in the solid solutions.",

keywords = "Antiferroelectric, Ceramics, Ferroelectric, Liquid phase sintering",

author = "Z. Ren and N. Zhang and S. Huo and Wong, \{J. Y.Y.\} and Ye, \{Z. G.\}",

year = "2014",

doi = "10.1080/00150193.2014.892409",

language = "英语",

volume = "464",

pages = "27--34",

journal = "Ferroelectrics",

issn = "0015-0193",

publisher = "Taylor and Francis Ltd.",

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}

TY - JOUR

T1 - Study of antiferroelectric PbZrO3-Pb(M1/2W 1/2)O3 (M = Mg, Zn & Mn) complex perovskite solid solutions

AU - Ren, Z.

AU - Zhang, N.

AU - Huo, S.

AU - Wong, J. Y.Y.

AU - Ye, Z. G.

PY - 2014

Y1 - 2014

N2 - Ceramics of the perovskite solid solution of 0.99PbZrO3-0. 01Pb(M1/2W1/2)O3 (M = Mg, Zn&Mn) have been prepared by the solid state reaction method. Their crystal structures and dielectric and antiferroelectric properties have been characterized. It is found that the crystal structure of the solid solutions remains in the orthorhombic Pbam symmetry with the addition of Pb(M1/2W1/2)O 3 up to 1 % while the induced polarization (PInd) is improved and the critical field (ECr) is decreased. The Curie temperature (TC) is also decreased with the substitution of Pb(M 1/2W1/2)O3 for PbZrO3 whereas the maximum permittivity (ε'max) is increased significantly. The grains of the ceramics are significantly grown, which could be attributed to the presence of a transient liquid phase in the solid solutions.

AB - Ceramics of the perovskite solid solution of 0.99PbZrO3-0. 01Pb(M1/2W1/2)O3 (M = Mg, Zn&Mn) have been prepared by the solid state reaction method. Their crystal structures and dielectric and antiferroelectric properties have been characterized. It is found that the crystal structure of the solid solutions remains in the orthorhombic Pbam symmetry with the addition of Pb(M1/2W1/2)O 3 up to 1 % while the induced polarization (PInd) is improved and the critical field (ECr) is decreased. The Curie temperature (TC) is also decreased with the substitution of Pb(M 1/2W1/2)O3 for PbZrO3 whereas the maximum permittivity (ε'max) is increased significantly. The grains of the ceramics are significantly grown, which could be attributed to the presence of a transient liquid phase in the solid solutions.

KW - Antiferroelectric

KW - Ceramics

KW - Ferroelectric

KW - Liquid phase sintering

UR - https://www.scopus.com/pages/publications/84900425075

U2 - 10.1080/00150193.2014.892409

DO - 10.1080/00150193.2014.892409

M3 - 文章

AN - SCOPUS:84900425075

SN - 0015-0193

VL - 464

SP - 27

EP - 34

JO - Ferroelectrics

JF - Ferroelectrics

IS - 1

ER -

Study of antiferroelectric PbZrO₃-Pb(M_1/2W _1/2)O₃ (M = Mg, Zn & Mn) complex perovskite solid solutions

Abstract

Keywords

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