Structure-Property Correlations in the Heterobimetallic 4f/3d Materials Ln2M(TeO3)2(SO4) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)

Jian Lin; Kariem Diefenbach; Mark A. Silver; Naresh S. Dalal; Thomas E. Albrecht-Schmitt

doi:10.1021/acs.cgd.5b00860

Structure-Property Correlations in the Heterobimetallic 4f/3d Materials Ln₂M(TeO₃)₂(SO₄) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)

Jian Lin
, Kariem Diefenbach
, Mark A. Silver
, Naresh S. Dalal
, Thomas E. Albrecht-Schmitt

Florida State University

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Eighteen new lanthanide transition metal heterobimetallic compounds, Ln₂Co(TeO₃)₂(SO₄)₂ (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu) and Ln₂Zn(TeO₃)₂(SO₄)₂ (Ln = Sm, Gd, Dy, Ho, Er, or Yb), have been prepared. They crystallize in triclinic space group P1Ì... with two different structural topologies occurring because of a reduction in the Ln³⁺ coordination number from eight to seven with the smallest lanthanides, Yb³⁺ and Lu³⁺. Magnetic susceptibility studies of compounds with diamagnetic lanthanides and lanthanide-like ions suggest that antiferromagnetic interactions occur between the Co²⁺ ions. Similarly, the replacement of Co²⁺ with Zn²⁺ yields Ln₂Zn(TeO₃)₂(SO₄)₂ (Ln = Gd, Dy, Ho, or Er), and these materials allow for the resolution of the nature of the interactions between lanthanide ions. The data suggest that the short-range Ln³⁺·Ln³⁺ interactions are ferromagnetic. However, a wide range of ferro- and antiferromagnetic interactions occur between the Ln³⁺ and the Co²⁺ cations, with several compounds exhibiting short-range magnetic correlations below 25 K. The results are discussed and contrasted with those recently reported for the related Ln₂Cu(TeO₃)₂(SO₄)₂ family. (Figure Presented).

Original language	English
Pages (from-to)	4606-4615
Number of pages	10
Journal	Crystal Growth and Design
Volume	15
Issue number	9
DOIs	https://doi.org/10.1021/acs.cgd.5b00860
State	Published - 2 Sep 2015
Externally published	Yes

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@article{f4d2a6c5702f4445858b580b8bc4e4e8,

title = "Structure-Property Correlations in the Heterobimetallic 4f/3d Materials Ln2M(TeO3)2(SO4) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)",

abstract = "Eighteen new lanthanide transition metal heterobimetallic compounds, Ln2Co(TeO3)2(SO4)2 (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu) and Ln2Zn(TeO3)2(SO4)2 (Ln = Sm, Gd, Dy, Ho, Er, or Yb), have been prepared. They crystallize in triclinic space group P1{\`I}... with two different structural topologies occurring because of a reduction in the Ln3+ coordination number from eight to seven with the smallest lanthanides, Yb3+ and Lu3+. Magnetic susceptibility studies of compounds with diamagnetic lanthanides and lanthanide-like ions suggest that antiferromagnetic interactions occur between the Co2+ ions. Similarly, the replacement of Co2+ with Zn2+ yields Ln2Zn(TeO3)2(SO4)2 (Ln = Gd, Dy, Ho, or Er), and these materials allow for the resolution of the nature of the interactions between lanthanide ions. The data suggest that the short-range Ln3+·Ln3+ interactions are ferromagnetic. However, a wide range of ferro- and antiferromagnetic interactions occur between the Ln3+ and the Co2+ cations, with several compounds exhibiting short-range magnetic correlations below 25 K. The results are discussed and contrasted with those recently reported for the related Ln2Cu(TeO3)2(SO4)2 family. (Figure Presented).",

author = "Jian Lin and Kariem Diefenbach and Silver, \{Mark A.\} and Dalal, \{Naresh S.\} and Albrecht-Schmitt, \{Thomas E.\}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = sep,

day = "2",

doi = "10.1021/acs.cgd.5b00860",

language = "英语",

volume = "15",

pages = "4606--4615",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Structure-Property Correlations in the Heterobimetallic 4f/3d Materials Ln2M(TeO3)2(SO4) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)

AU - Lin, Jian

AU - Diefenbach, Kariem

AU - Silver, Mark A.

AU - Dalal, Naresh S.

AU - Albrecht-Schmitt, Thomas E.

PY - 2015/9/2

Y1 - 2015/9/2

N2 - Eighteen new lanthanide transition metal heterobimetallic compounds, Ln2Co(TeO3)2(SO4)2 (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu) and Ln2Zn(TeO3)2(SO4)2 (Ln = Sm, Gd, Dy, Ho, Er, or Yb), have been prepared. They crystallize in triclinic space group P1Ì... with two different structural topologies occurring because of a reduction in the Ln3+ coordination number from eight to seven with the smallest lanthanides, Yb3+ and Lu3+. Magnetic susceptibility studies of compounds with diamagnetic lanthanides and lanthanide-like ions suggest that antiferromagnetic interactions occur between the Co2+ ions. Similarly, the replacement of Co2+ with Zn2+ yields Ln2Zn(TeO3)2(SO4)2 (Ln = Gd, Dy, Ho, or Er), and these materials allow for the resolution of the nature of the interactions between lanthanide ions. The data suggest that the short-range Ln3+·Ln3+ interactions are ferromagnetic. However, a wide range of ferro- and antiferromagnetic interactions occur between the Ln3+ and the Co2+ cations, with several compounds exhibiting short-range magnetic correlations below 25 K. The results are discussed and contrasted with those recently reported for the related Ln2Cu(TeO3)2(SO4)2 family. (Figure Presented).

AB - Eighteen new lanthanide transition metal heterobimetallic compounds, Ln2Co(TeO3)2(SO4)2 (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu) and Ln2Zn(TeO3)2(SO4)2 (Ln = Sm, Gd, Dy, Ho, Er, or Yb), have been prepared. They crystallize in triclinic space group P1Ì... with two different structural topologies occurring because of a reduction in the Ln3+ coordination number from eight to seven with the smallest lanthanides, Yb3+ and Lu3+. Magnetic susceptibility studies of compounds with diamagnetic lanthanides and lanthanide-like ions suggest that antiferromagnetic interactions occur between the Co2+ ions. Similarly, the replacement of Co2+ with Zn2+ yields Ln2Zn(TeO3)2(SO4)2 (Ln = Gd, Dy, Ho, or Er), and these materials allow for the resolution of the nature of the interactions between lanthanide ions. The data suggest that the short-range Ln3+·Ln3+ interactions are ferromagnetic. However, a wide range of ferro- and antiferromagnetic interactions occur between the Ln3+ and the Co2+ cations, with several compounds exhibiting short-range magnetic correlations below 25 K. The results are discussed and contrasted with those recently reported for the related Ln2Cu(TeO3)2(SO4)2 family. (Figure Presented).

UR - https://www.scopus.com/pages/publications/84940977474

U2 - 10.1021/acs.cgd.5b00860

DO - 10.1021/acs.cgd.5b00860

M3 - 文章

AN - SCOPUS:84940977474

SN - 1528-7483

VL - 15

SP - 4606

EP - 4615

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 9

ER -

Structure-Property Correlations in the Heterobimetallic 4f/3d Materials Ln₂M(TeO₃)₂(SO₄) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)

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