Structural transitions in [001]/[111]-oriented 0.26Pb(In 1/2Nb1/2)O3-0.46Pb(Mg1/3Nb 2/3)O3-0.28PbTiO3 single crystals probed via neutron diffraction and electrical characterization

Qian Li; Yun Liu; Jian Wang; Andrew J. Studer; Ray L. Withers; Zhenrong Li; Zhuo Xu

doi:10.1063/1.4802669

Structural transitions in [001]/[111]-oriented 0.26Pb(In _1/2Nb_1/2)O₃-0.46Pb(Mg_1/3Nb _2/3)O₃-0.28PbTiO₃ single crystals probed via neutron diffraction and electrical characterization

Qian Li
, Yun Liu
, Jian Wang
, Andrew J. Studer
, Ray L. Withers
, Zhenrong Li
, Zhuo Xu

Faculty of Electronic and Information Engineering

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

We report changes in the metric symmetry of unpoled and electrically poled single crystals of 0.26Pb(In_1/2Nb_1/2)O₃-0. 46Pb(Mg_1/3Nb_2/3)O₃-0.28PbTiO₃, as revealed by neutron diffraction in conjunction with electrical measurements. The unpoled crystals show relaxor characteristics and an average rhombohedral symmetry that persists from ambient temperature up to the Curie temperature of ∼165 °C. Poling along a [111] direction enhances the rhombohedral distortion away from cubic metric symmetry but appears not to induce any monoclinic phases. By contrast, the poled [001]-oriented crystal has orthorhombic (or monoclinic M_C) metric symmetry at 25 °C. An intermediate transition to a metrically tetragonal phase around 120 °C is confirmed for both poled crystals.

Original language	English
Article number	154104
Journal	Journal of Applied Physics
Volume	113
Issue number	15
DOIs	https://doi.org/10.1063/1.4802669
State	Published - Apr 2013

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@article{27425627c11d4bc5ba6510a7f43af227,

title = "Structural transitions in [001]/[111]-oriented 0.26Pb(In 1/2Nb1/2)O3-0.46Pb(Mg1/3Nb 2/3)O3-0.28PbTiO3 single crystals probed via neutron diffraction and electrical characterization",

abstract = "We report changes in the metric symmetry of unpoled and electrically poled single crystals of 0.26Pb(In1/2Nb1/2)O3-0. 46Pb(Mg1/3Nb2/3)O3-0.28PbTiO3, as revealed by neutron diffraction in conjunction with electrical measurements. The unpoled crystals show relaxor characteristics and an average rhombohedral symmetry that persists from ambient temperature up to the Curie temperature of ∼165 °C. Poling along a [111] direction enhances the rhombohedral distortion away from cubic metric symmetry but appears not to induce any monoclinic phases. By contrast, the poled [001]-oriented crystal has orthorhombic (or monoclinic MC) metric symmetry at 25 °C. An intermediate transition to a metrically tetragonal phase around 120 °C is confirmed for both poled crystals.",

author = "Qian Li and Yun Liu and Jian Wang and Studer, \{Andrew J.\} and Withers, \{Ray L.\} and Zhenrong Li and Zhuo Xu",

year = "2013",

month = apr,

doi = "10.1063/1.4802669",

language = "英语",

volume = "113",

journal = "Journal of Applied Physics",

issn = "0021-8979",

publisher = "American Institute of Physics",

number = "15",

}

TY - JOUR

T1 - Structural transitions in [001]/[111]-oriented 0.26Pb(In 1/2Nb1/2)O3-0.46Pb(Mg1/3Nb 2/3)O3-0.28PbTiO3 single crystals probed via neutron diffraction and electrical characterization

AU - Li, Qian

AU - Liu, Yun

AU - Wang, Jian

AU - Studer, Andrew J.

AU - Withers, Ray L.

AU - Li, Zhenrong

AU - Xu, Zhuo

PY - 2013/4

Y1 - 2013/4

N2 - We report changes in the metric symmetry of unpoled and electrically poled single crystals of 0.26Pb(In1/2Nb1/2)O3-0. 46Pb(Mg1/3Nb2/3)O3-0.28PbTiO3, as revealed by neutron diffraction in conjunction with electrical measurements. The unpoled crystals show relaxor characteristics and an average rhombohedral symmetry that persists from ambient temperature up to the Curie temperature of ∼165 °C. Poling along a [111] direction enhances the rhombohedral distortion away from cubic metric symmetry but appears not to induce any monoclinic phases. By contrast, the poled [001]-oriented crystal has orthorhombic (or monoclinic MC) metric symmetry at 25 °C. An intermediate transition to a metrically tetragonal phase around 120 °C is confirmed for both poled crystals.

AB - We report changes in the metric symmetry of unpoled and electrically poled single crystals of 0.26Pb(In1/2Nb1/2)O3-0. 46Pb(Mg1/3Nb2/3)O3-0.28PbTiO3, as revealed by neutron diffraction in conjunction with electrical measurements. The unpoled crystals show relaxor characteristics and an average rhombohedral symmetry that persists from ambient temperature up to the Curie temperature of ∼165 °C. Poling along a [111] direction enhances the rhombohedral distortion away from cubic metric symmetry but appears not to induce any monoclinic phases. By contrast, the poled [001]-oriented crystal has orthorhombic (or monoclinic MC) metric symmetry at 25 °C. An intermediate transition to a metrically tetragonal phase around 120 °C is confirmed for both poled crystals.

UR - https://www.scopus.com/pages/publications/84884293232

U2 - 10.1063/1.4802669

DO - 10.1063/1.4802669

M3 - 文章

AN - SCOPUS:84884293232

SN - 0021-8979

VL - 113

JO - Journal of Applied Physics

JF - Journal of Applied Physics

IS - 15

M1 - 154104

ER -

Structural transitions in [001]/[111]-oriented 0.26Pb(In _1/2Nb_1/2)O₃-0.46Pb(Mg_1/3Nb _2/3)O₃-0.28PbTiO₃ single crystals probed via neutron diffraction and electrical characterization

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