Structural diversity of four metal-organic frameworks based on linear homo/heterotrinuclear nodes with furan-2,5-dicarboxylic acid: Crystal structures and luminescent and magnetic properties

Huan Huan Li; Wei Shi; Na Xu; Zhen Jie Zhang; Zheng Niu; Tian Han; Peng Cheng

doi:10.1021/cg300196w

Structural diversity of four metal-organic frameworks based on linear homo/heterotrinuclear nodes with furan-2,5-dicarboxylic acid: Crystal structures and luminescent and magnetic properties

Huan Huan Li
, Wei Shi
, Na Xu
, Zhen Jie Zhang
, Zheng Niu
, Tian Han
, Peng Cheng

Nankai University

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Four new homo- and heterometallic metal-organic frameworks (MOFs) based on linear homo/heterotrinuclear nodes, namely, {[NH ₂(CH ₃) ₂] ₂[Co ₃(FDA) ₄(CH ₃OH) ₂]} _n (1), {[NH ₂(CH ₃) ₂] ₂[Co ₃(FDA) ₄] •2DMF} _n (2), {[Gd ₂Co(FDA) ₄(H ₂O) ₄]•2H ₂O} _n (3), and {[Dy ₂Co(FDA) ₄(glycol) ₂]•2H ₂O} _n (4) (H ₂FDA = furan-2,5-dicarboxylic acid), were obtained under solvothermal conditions and characterized by single crystal X-ray diffraction, magnetic susceptibility, and luminescence measurements. The building blocks of four MOFs are linear trinuclear clusters stabilized by carboxylic groups, but the three-dimensional frameworks are different. MOFs 1 and 2 are both pcu nets with a point symbol of (4 ¹².6 ³), whereas MOFs 3 and 4 exhibit 3,10T9 and tfz-d nets with the point symbols of (4 ¹⁸.6 ²⁴.8 ³)(4 ³) ₂ and (4 ³) ₂(4 ⁶.6 ¹⁸.8 ⁴), respectively. Magnetic susceptibility measurements indicate that there are antiferromagnetic interactions in 1-3, while 4 displays interesting ferromagnetic interactions between Co(II) and Dy(III) ions. Luminescence investigation of 4 shows intense and characteristic emission bands of Dy(III) ions in the solid state.

Original language	English
Pages (from-to)	2602-2612
Number of pages	11
Journal	Crystal Growth and Design
Volume	12
Issue number	5
DOIs	https://doi.org/10.1021/cg300196w
State	Published - 2 May 2012
Externally published	Yes

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@article{b9d2551cfcea42dcb48ef655db7d715b,

title = "Structural diversity of four metal-organic frameworks based on linear homo/heterotrinuclear nodes with furan-2,5-dicarboxylic acid: Crystal structures and luminescent and magnetic properties",

abstract = "Four new homo- and heterometallic metal-organic frameworks (MOFs) based on linear homo/heterotrinuclear nodes, namely, \{[NH 2(CH 3) 2] 2[Co 3(FDA) 4(CH 3OH) 2]\} n (1), \{[NH 2(CH 3) 2] 2[Co 3(FDA) 4] •2DMF\} n (2), \{[Gd 2Co(FDA) 4(H 2O) 4]•2H 2O\} n (3), and \{[Dy 2Co(FDA) 4(glycol) 2]•2H 2O\} n (4) (H 2FDA = furan-2,5-dicarboxylic acid), were obtained under solvothermal conditions and characterized by single crystal X-ray diffraction, magnetic susceptibility, and luminescence measurements. The building blocks of four MOFs are linear trinuclear clusters stabilized by carboxylic groups, but the three-dimensional frameworks are different. MOFs 1 and 2 are both pcu nets with a point symbol of (4 12.6 3), whereas MOFs 3 and 4 exhibit 3,10T9 and tfz-d nets with the point symbols of (4 18.6 24.8 3)(4 3) 2 and (4 3) 2(4 6.6 18.8 4), respectively. Magnetic susceptibility measurements indicate that there are antiferromagnetic interactions in 1-3, while 4 displays interesting ferromagnetic interactions between Co(II) and Dy(III) ions. Luminescence investigation of 4 shows intense and characteristic emission bands of Dy(III) ions in the solid state.",

author = "Li, \{Huan Huan\} and Wei Shi and Na Xu and Zhang, \{Zhen Jie\} and Zheng Niu and Tian Han and Peng Cheng",

year = "2012",

month = may,

day = "2",

doi = "10.1021/cg300196w",

language = "英语",

volume = "12",

pages = "2602--2612",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "5",

}

Structural diversity of four metal-organic frameworks based on linear homo/heterotrinuclear nodes with furan-2,5-dicarboxylic acid: Crystal structures and luminescent and magnetic properties. / Li, Huan Huan; Shi, Wei; Xu, Na et al.
In: Crystal Growth and Design, Vol. 12, No. 5, 02.05.2012, p. 2602-2612.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Structural diversity of four metal-organic frameworks based on linear homo/heterotrinuclear nodes with furan-2,5-dicarboxylic acid

T2 - Crystal structures and luminescent and magnetic properties

AU - Li, Huan Huan

AU - Shi, Wei

AU - Xu, Na

AU - Zhang, Zhen Jie

AU - Niu, Zheng

AU - Han, Tian

AU - Cheng, Peng

PY - 2012/5/2

Y1 - 2012/5/2

N2 - Four new homo- and heterometallic metal-organic frameworks (MOFs) based on linear homo/heterotrinuclear nodes, namely, {[NH 2(CH 3) 2] 2[Co 3(FDA) 4(CH 3OH) 2]} n (1), {[NH 2(CH 3) 2] 2[Co 3(FDA) 4] •2DMF} n (2), {[Gd 2Co(FDA) 4(H 2O) 4]•2H 2O} n (3), and {[Dy 2Co(FDA) 4(glycol) 2]•2H 2O} n (4) (H 2FDA = furan-2,5-dicarboxylic acid), were obtained under solvothermal conditions and characterized by single crystal X-ray diffraction, magnetic susceptibility, and luminescence measurements. The building blocks of four MOFs are linear trinuclear clusters stabilized by carboxylic groups, but the three-dimensional frameworks are different. MOFs 1 and 2 are both pcu nets with a point symbol of (4 12.6 3), whereas MOFs 3 and 4 exhibit 3,10T9 and tfz-d nets with the point symbols of (4 18.6 24.8 3)(4 3) 2 and (4 3) 2(4 6.6 18.8 4), respectively. Magnetic susceptibility measurements indicate that there are antiferromagnetic interactions in 1-3, while 4 displays interesting ferromagnetic interactions between Co(II) and Dy(III) ions. Luminescence investigation of 4 shows intense and characteristic emission bands of Dy(III) ions in the solid state.

AB - Four new homo- and heterometallic metal-organic frameworks (MOFs) based on linear homo/heterotrinuclear nodes, namely, {[NH 2(CH 3) 2] 2[Co 3(FDA) 4(CH 3OH) 2]} n (1), {[NH 2(CH 3) 2] 2[Co 3(FDA) 4] •2DMF} n (2), {[Gd 2Co(FDA) 4(H 2O) 4]•2H 2O} n (3), and {[Dy 2Co(FDA) 4(glycol) 2]•2H 2O} n (4) (H 2FDA = furan-2,5-dicarboxylic acid), were obtained under solvothermal conditions and characterized by single crystal X-ray diffraction, magnetic susceptibility, and luminescence measurements. The building blocks of four MOFs are linear trinuclear clusters stabilized by carboxylic groups, but the three-dimensional frameworks are different. MOFs 1 and 2 are both pcu nets with a point symbol of (4 12.6 3), whereas MOFs 3 and 4 exhibit 3,10T9 and tfz-d nets with the point symbols of (4 18.6 24.8 3)(4 3) 2 and (4 3) 2(4 6.6 18.8 4), respectively. Magnetic susceptibility measurements indicate that there are antiferromagnetic interactions in 1-3, while 4 displays interesting ferromagnetic interactions between Co(II) and Dy(III) ions. Luminescence investigation of 4 shows intense and characteristic emission bands of Dy(III) ions in the solid state.

UR - https://www.scopus.com/pages/publications/84860461346

U2 - 10.1021/cg300196w

DO - 10.1021/cg300196w

M3 - 文章

AN - SCOPUS:84860461346

SN - 1528-7483

VL - 12

SP - 2602

EP - 2612

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 5

ER -

Structural diversity of four metal-organic frameworks based on linear homo/heterotrinuclear nodes with furan-2,5-dicarboxylic acid: Crystal structures and luminescent and magnetic properties

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