Structural diversity and photoluminescent properties of two Mn(II) sulfoterephthalate complexes from multi-pyridine N-containing ligands

Yi Xia Ren; Miao An; Lou Jun Gao; Hong Mei Chai; Xiang Yang Hou; Gui Jiang Zhou

doi:10.14102/j.cnki.0254-5861.2011-0874

Structural diversity and photoluminescent properties of two Mn(II) sulfoterephthalate complexes from multi-pyridine N-containing ligands

Yi Xia Ren
, Miao An
, Lou Jun Gao
, Hong Mei Chai
, Xiang Yang Hou
, Gui Jiang Zhou

School of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Solvothermal reaction of manganese(II) salt with monosodium 2-sulfoterephthalate (2-NaH2stp) and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with [Mn₂(Hstp) ₂ (bpp) ₂ (H₂O)₄] (1) and [Mn₃ (stp) ₂ (tpy) ₃ (H₂O)](H₂O) ₅ (2) (bpp = benz-2,3-pyrimidine-[2,3-f]-1,10-phenanthroline, tpy = 2,2′:6′,2′′-terpyridine). X-ray diffraction structural analyses of two complexes reveal their structural diversity (0D and 1D) due to the difference of auxiliary ligands. 1 is a discrete structure, in which the Mn(II) ion is hexa-coordinated with one stp, one bpp ligand and two water molecules. Complex 2 is a one-dimensional (1D) chain-like structure with three crystallographically independent Mn(II) ions. The photoluminescent properties could be assigned to the π-π∗ transition of 2-sulfoterephthalate ligands.

Original language	English
Pages (from-to)	550-558
Number of pages	9
Journal	Jiegou Huaxue
Volume	35
Issue number	4
DOIs	https://doi.org/10.14102/j.cnki.0254-5861.2011-0874
State	Published - 12 Apr 2016

Keywords

Photoluminescent property
Solvothermal reaction
Structural diversity

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10.14102/j.cnki.0254-5861.2011-0874

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@article{558960e73a06448dae514eb092640f10,

title = "Structural diversity and photoluminescent properties of two Mn(II) sulfoterephthalate complexes from multi-pyridine N-containing ligands",

abstract = "Solvothermal reaction of manganese(II) salt with monosodium 2-sulfoterephthalate (2-NaH2stp) and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with [Mn2(Hstp) 2 (bpp) 2 (H2O)4] (1) and [Mn3 (stp) 2 (tpy) 3 (H2O)](H2O) 5 (2) (bpp = benz-2,3-pyrimidine-[2,3-f]-1,10-phenanthroline, tpy = 2,2′:6′,2′′-terpyridine). X-ray diffraction structural analyses of two complexes reveal their structural diversity (0D and 1D) due to the difference of auxiliary ligands. 1 is a discrete structure, in which the Mn(II) ion is hexa-coordinated with one stp, one bpp ligand and two water molecules. Complex 2 is a one-dimensional (1D) chain-like structure with three crystallographically independent Mn(II) ions. The photoluminescent properties could be assigned to the π-π∗ transition of 2-sulfoterephthalate ligands.",

keywords = "Photoluminescent property, Solvothermal reaction, Structural diversity",

author = "Ren, \{Yi Xia\} and Miao An and Gao, \{Lou Jun\} and Chai, \{Hong Mei\} and Hou, \{Xiang Yang\} and Zhou, \{Gui Jiang\}",

year = "2016",

month = apr,

day = "12",

doi = "10.14102/j.cnki.0254-5861.2011-0874",

language = "英语",

volume = "35",

pages = "550--558",

journal = "Jiegou Huaxue",

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publisher = "Fujian Institute of Research of the Structure of Matter",

number = "4",

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T1 - Structural diversity and photoluminescent properties of two Mn(II) sulfoterephthalate complexes from multi-pyridine N-containing ligands

AU - Ren, Yi Xia

AU - An, Miao

AU - Gao, Lou Jun

AU - Chai, Hong Mei

AU - Hou, Xiang Yang

AU - Zhou, Gui Jiang

PY - 2016/4/12

Y1 - 2016/4/12

N2 - Solvothermal reaction of manganese(II) salt with monosodium 2-sulfoterephthalate (2-NaH2stp) and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with [Mn2(Hstp) 2 (bpp) 2 (H2O)4] (1) and [Mn3 (stp) 2 (tpy) 3 (H2O)](H2O) 5 (2) (bpp = benz-2,3-pyrimidine-[2,3-f]-1,10-phenanthroline, tpy = 2,2′:6′,2′′-terpyridine). X-ray diffraction structural analyses of two complexes reveal their structural diversity (0D and 1D) due to the difference of auxiliary ligands. 1 is a discrete structure, in which the Mn(II) ion is hexa-coordinated with one stp, one bpp ligand and two water molecules. Complex 2 is a one-dimensional (1D) chain-like structure with three crystallographically independent Mn(II) ions. The photoluminescent properties could be assigned to the π-π∗ transition of 2-sulfoterephthalate ligands.

AB - Solvothermal reaction of manganese(II) salt with monosodium 2-sulfoterephthalate (2-NaH2stp) and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with [Mn2(Hstp) 2 (bpp) 2 (H2O)4] (1) and [Mn3 (stp) 2 (tpy) 3 (H2O)](H2O) 5 (2) (bpp = benz-2,3-pyrimidine-[2,3-f]-1,10-phenanthroline, tpy = 2,2′:6′,2′′-terpyridine). X-ray diffraction structural analyses of two complexes reveal their structural diversity (0D and 1D) due to the difference of auxiliary ligands. 1 is a discrete structure, in which the Mn(II) ion is hexa-coordinated with one stp, one bpp ligand and two water molecules. Complex 2 is a one-dimensional (1D) chain-like structure with three crystallographically independent Mn(II) ions. The photoluminescent properties could be assigned to the π-π∗ transition of 2-sulfoterephthalate ligands.

KW - Photoluminescent property

KW - Solvothermal reaction

KW - Structural diversity

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U2 - 10.14102/j.cnki.0254-5861.2011-0874

DO - 10.14102/j.cnki.0254-5861.2011-0874

M3 - 文章

AN - SCOPUS:84973442805

SN - 0254-5861

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ER -

Structural diversity and photoluminescent properties of two Mn(II) sulfoterephthalate complexes from multi-pyridine N-containing ligands

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