S2O8 2-/Al-O-MCM-41 catalysts for the esterification of acetic acid with n-butanol: Influences of the preparation conditions on catalytic performances

Long Chen; Junxia Wang; Dawei Meng; Hui Pan; Guanghui Su; Ying Xiao; Zhifei Yan

doi:10.1007/s11144-013-0566-1

S₂O₈ ^2-/Al-O-MCM-41 catalysts for the esterification of acetic acid with n-butanol: Influences of the preparation conditions on catalytic performances

Long Chen
, Junxia Wang
, Dawei Meng
, Hui Pan
, Guanghui Su
, Ying Xiao
, Zhifei Yan

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

S₂O₈ ^2-/Al-O-MCM-41 solid acid catalysts were prepared by the sol-gel method. Their catalytic performances were evaluated by the esterification reaction of acetic acid with n-butanol. The characterization of prepared catalysts was performed by means of XRD, IR, TG-DSC and SEM. The experimental results showed that the S₂O₈ ^2-/Al-O-MCM-41 solid acid catalyst exhibited an optimal catalytic performance with ca. 99.00 % esterification efficiency under the optimum synthesis conditions. In addition, it kept its high activity with 93.17 % esterification efficiency even after being used for seven times, which indicated that S₂O₈ ^2-/Al-O-MCM-41 solid acid catalyst had excellent reusability.

Original language	English
Pages (from-to)	575-587
Number of pages	13
Journal	Reaction Kinetics, Mechanisms and Catalysis
Volume	109
Issue number	2
DOIs	https://doi.org/10.1007/s11144-013-0566-1
State	Published - Aug 2013
Externally published	Yes

Keywords

Catalytic performances
Esterification
Reusability
SO /Al-O-MCM-41
Solid acid

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10.1007/s11144-013-0566-1

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title = "S2O8 2-/Al-O-MCM-41 catalysts for the esterification of acetic acid with n-butanol: Influences of the preparation conditions on catalytic performances",

abstract = "S2O8 2-/Al-O-MCM-41 solid acid catalysts were prepared by the sol-gel method. Their catalytic performances were evaluated by the esterification reaction of acetic acid with n-butanol. The characterization of prepared catalysts was performed by means of XRD, IR, TG-DSC and SEM. The experimental results showed that the S2O8 2-/Al-O-MCM-41 solid acid catalyst exhibited an optimal catalytic performance with ca. 99.00 \% esterification efficiency under the optimum synthesis conditions. In addition, it kept its high activity with 93.17 \% esterification efficiency even after being used for seven times, which indicated that S2O8 2-/Al-O-MCM-41 solid acid catalyst had excellent reusability.",

keywords = "Catalytic performances, Esterification, Reusability, SO /Al-O-MCM-41, Solid acid",

author = "Long Chen and Junxia Wang and Dawei Meng and Hui Pan and Guanghui Su and Ying Xiao and Zhifei Yan",

year = "2013",

month = aug,

doi = "10.1007/s11144-013-0566-1",

language = "英语",

volume = "109",

pages = "575--587",

journal = "Reaction Kinetics, Mechanisms and Catalysis",

issn = "1878-5190",

publisher = "Springer Science and Business Media B.V.",

number = "2",

}

TY - JOUR

T1 - S2O8 2-/Al-O-MCM-41 catalysts for the esterification of acetic acid with n-butanol

T2 - Influences of the preparation conditions on catalytic performances

AU - Chen, Long

AU - Wang, Junxia

AU - Meng, Dawei

AU - Pan, Hui

AU - Su, Guanghui

AU - Xiao, Ying

AU - Yan, Zhifei

PY - 2013/8

Y1 - 2013/8

N2 - S2O8 2-/Al-O-MCM-41 solid acid catalysts were prepared by the sol-gel method. Their catalytic performances were evaluated by the esterification reaction of acetic acid with n-butanol. The characterization of prepared catalysts was performed by means of XRD, IR, TG-DSC and SEM. The experimental results showed that the S2O8 2-/Al-O-MCM-41 solid acid catalyst exhibited an optimal catalytic performance with ca. 99.00 % esterification efficiency under the optimum synthesis conditions. In addition, it kept its high activity with 93.17 % esterification efficiency even after being used for seven times, which indicated that S2O8 2-/Al-O-MCM-41 solid acid catalyst had excellent reusability.

AB - S2O8 2-/Al-O-MCM-41 solid acid catalysts were prepared by the sol-gel method. Their catalytic performances were evaluated by the esterification reaction of acetic acid with n-butanol. The characterization of prepared catalysts was performed by means of XRD, IR, TG-DSC and SEM. The experimental results showed that the S2O8 2-/Al-O-MCM-41 solid acid catalyst exhibited an optimal catalytic performance with ca. 99.00 % esterification efficiency under the optimum synthesis conditions. In addition, it kept its high activity with 93.17 % esterification efficiency even after being used for seven times, which indicated that S2O8 2-/Al-O-MCM-41 solid acid catalyst had excellent reusability.

KW - Catalytic performances

KW - Esterification

KW - Reusability

KW - SO /Al-O-MCM-41

KW - Solid acid

UR - https://www.scopus.com/pages/publications/84880922501

U2 - 10.1007/s11144-013-0566-1

DO - 10.1007/s11144-013-0566-1

M3 - 文章

AN - SCOPUS:84880922501

SN - 1878-5190

VL - 109

SP - 575

EP - 587

JO - Reaction Kinetics, Mechanisms and Catalysis

JF - Reaction Kinetics, Mechanisms and Catalysis

IS - 2

ER -

S₂O₈ ^2-/Al-O-MCM-41 catalysts for the esterification of acetic acid with n-butanol: Influences of the preparation conditions on catalytic performances

Abstract

Keywords

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