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Speed of sound for ethanol in vicinity of the critical point from Rayleigh-Brillouin light scattering spectroscopy

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Abstract

The speed of sound in ethanol was measured in liquid, near-critical and supercritical fluid over the temperature range from (298.52–655.67) K along five isobaric lines from (0.1–9.0) MPa from Rayleigh-Brillouin light scattering spectroscopy. The expanded relative uncertainty for the reported speed of sound is estimated to be 1.3% with the level of confidence of 0.95 (coverage factor k = 2). The correlation for experimental speeds of sound in liquid ethanol are presented, and the averaged absolute percentage deviation between the calculated values and literature data is 0.16%. The variation tendencies of the speed of sound in ethanol with increasing temperature and pressure were illustrated over the whole investigated p-T region. The accuracy of the three fundamental equations available in the NIST Standard Reference Database 23 were assessed by the experimental speeds of sound in ethanol.

Original languageEnglish
Article number112585
JournalFluid Phase Equilibria
Volume515
DOIs
StatePublished - 1 Jul 2020

Keywords

  • Brillouin frequency shift
  • Correlation
  • EOS
  • Ethanol
  • Speed of sound

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