Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation

Huangjie Lu; Xiaojing Guo; Yaxing Wang; Kariem Diefenbach; Lanhua Chen; Jian Qiang Wang; Jian Lin; Shuao Wang

doi:10.1039/c9dt02387a

Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation

Huangjie Lu
, Xiaojing Guo
, Yaxing Wang
, Kariem Diefenbach
, Lanhua Chen
, Jian Qiang Wang
, Jian Lin
, Shuao Wang

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A unique selective crystallization strategy based on an iodate-sulfate mixed-anion system has been developed for lanthanide separation. Periodic divergences in crystal formation energy enable simple Nd/Dy, La/Lu, Gd/Tb, La/Dy, and Nd/Lu separations through crystallization of the early lanthanides, giving rise to separation factors up to 123(5), 100(2), 2.4(2), 137(9), and 85(6), respectively.

Original language	English
Pages (from-to)	12808-12811
Number of pages	4
Journal	Dalton Transactions
Volume	48
Issue number	34
DOIs	https://doi.org/10.1039/c9dt02387a
State	Published - 2019
Externally published	Yes

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title = "Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation",

abstract = "A unique selective crystallization strategy based on an iodate-sulfate mixed-anion system has been developed for lanthanide separation. Periodic divergences in crystal formation energy enable simple Nd/Dy, La/Lu, Gd/Tb, La/Dy, and Nd/Lu separations through crystallization of the early lanthanides, giving rise to separation factors up to 123(5), 100(2), 2.4(2), 137(9), and 85(6), respectively.",

author = "Huangjie Lu and Xiaojing Guo and Yaxing Wang and Kariem Diefenbach and Lanhua Chen and Wang, \{Jian Qiang\} and Jian Lin and Shuao Wang",

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doi = "10.1039/c9dt02387a",

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volume = "48",

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TY - JOUR

T1 - Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation

AU - Lu, Huangjie

AU - Guo, Xiaojing

AU - Wang, Yaxing

AU - Diefenbach, Kariem

AU - Chen, Lanhua

AU - Wang, Jian Qiang

AU - Lin, Jian

AU - Wang, Shuao

PY - 2019

Y1 - 2019

N2 - A unique selective crystallization strategy based on an iodate-sulfate mixed-anion system has been developed for lanthanide separation. Periodic divergences in crystal formation energy enable simple Nd/Dy, La/Lu, Gd/Tb, La/Dy, and Nd/Lu separations through crystallization of the early lanthanides, giving rise to separation factors up to 123(5), 100(2), 2.4(2), 137(9), and 85(6), respectively.

AB - A unique selective crystallization strategy based on an iodate-sulfate mixed-anion system has been developed for lanthanide separation. Periodic divergences in crystal formation energy enable simple Nd/Dy, La/Lu, Gd/Tb, La/Dy, and Nd/Lu separations through crystallization of the early lanthanides, giving rise to separation factors up to 123(5), 100(2), 2.4(2), 137(9), and 85(6), respectively.

UR - https://www.scopus.com/pages/publications/85071668349

U2 - 10.1039/c9dt02387a

DO - 10.1039/c9dt02387a

M3 - 文章

C2 - 31348473

AN - SCOPUS:85071668349

SN - 1477-9226

VL - 48

SP - 12808

EP - 12811

JO - Dalton Transactions

JF - Dalton Transactions

IS - 34

ER -

Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation

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