Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2

Monika Vogt; Chao Wu; Allen G. Oliver; Christopher J. Meyer; William F. Schneider; Brandon L. Ashfeld

doi:10.1039/c3cc46555a

Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO₂

Monika Vogt
, Chao Wu
, Allen G. Oliver
, Christopher J. Meyer
, William F. Schneider
, Brandon L. Ashfeld

Frontier Institute of Science and Technology

University of Notre Dame

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Herein, we report experimental and computational results for the carboxylation of abnormal anionic N-heterocyclic dicarbenes (NHDCs) with CO₂. Under ambient dosing conditions, carbonyl addition occurs selectively at C4 without a second carboxylation event occurring at the C2 carbene center.

Original language	English
Pages (from-to)	11527-11529
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	98
DOIs	https://doi.org/10.1039/c3cc46555a
State	Published - 14 Nov 2013

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title = "Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2",

abstract = "Herein, we report experimental and computational results for the carboxylation of abnormal anionic N-heterocyclic dicarbenes (NHDCs) with CO2. Under ambient dosing conditions, carbonyl addition occurs selectively at C4 without a second carboxylation event occurring at the C2 carbene center.",

author = "Monika Vogt and Chao Wu and Oliver, \{Allen G.\} and Meyer, \{Christopher J.\} and Schneider, \{William F.\} and Ashfeld, \{Brandon L.\}",

year = "2013",

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doi = "10.1039/c3cc46555a",

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T1 - Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2

AU - Vogt, Monika

AU - Wu, Chao

AU - Oliver, Allen G.

AU - Meyer, Christopher J.

AU - Schneider, William F.

AU - Ashfeld, Brandon L.

PY - 2013/11/14

Y1 - 2013/11/14

N2 - Herein, we report experimental and computational results for the carboxylation of abnormal anionic N-heterocyclic dicarbenes (NHDCs) with CO2. Under ambient dosing conditions, carbonyl addition occurs selectively at C4 without a second carboxylation event occurring at the C2 carbene center.

AB - Herein, we report experimental and computational results for the carboxylation of abnormal anionic N-heterocyclic dicarbenes (NHDCs) with CO2. Under ambient dosing conditions, carbonyl addition occurs selectively at C4 without a second carboxylation event occurring at the C2 carbene center.

UR - https://www.scopus.com/pages/publications/84887894990

U2 - 10.1039/c3cc46555a

DO - 10.1039/c3cc46555a

M3 - 文章

C2 - 24177269

AN - SCOPUS:84887894990

SN - 1359-7345

VL - 49

SP - 11527

EP - 11529

JO - Chemical Communications

JF - Chemical Communications

IS - 98

ER -

Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO₂

Abstract

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