Significantly enhanced photothermal catalytic hydrogen evolution over Cu₂O-rGO/TiO₂ composite with full spectrum solar light

Reduced graphene oxide (rGO) has conspicuous photothermal characteristics in photothermal applications. Thus in our previous work, we used reduced graphene oxide (rGO) supported titanium dioxide (TiO₂) nanocomposite (rGO/TiO₂) to absorb the ultraviolet and infrared light in the photothermal hydrogen evolution process. In order to make use of the full spectrum solar energy into other clear energy, the visible light should be also considered in following research. Herein, we report a cuprous oxide (Cu₂O) decorated reduced graphene oxide (rGO) supported titanium dioxide (TiO₂) (Cu₂O-rGO/TiO₂) catalysts, which can absorb full spectrum solar light in an innovative way. The Cu₂O-rGO/TiO₂ catalyst is synthesized through a one-step hydrothermal method. The rates of hydrogen evolution are 17800 μmol·g^-1h⁻¹ under photothermal condition (90°C), 3800 μmol·g^-1h⁻¹ under photocatalysis condition only (25°C) and 0 μmol·g^-1h⁻¹ under thermal catalysis condition only. The result of photothermal catalytic hydrogen evolution rate is about 4.7 times that of the sum of the photocatalytic and thermal reactions. The photothermal synergetic effect promotes the photo-generated electron-holes separation through the rGO due to the temperature rising, and accelerates the reaction rates on the catalyst surface in hydrogen evolution process simultaneously. This work could provide us a new promising way for the conversion of full spectrum solar energy to hydrogen energy.