Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock

Yang Li; Haoquan Li; Henrik Junge; Matthias Beller

doi:10.1039/c4cc06933a

Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock

Yang Li
, Haoquan Li
, Henrik Junge
, Matthias Beller

Leibniz Institute for Catalysis

Research output: Contribution to journal › Article › peer-review

92 Scopus citations

Abstract

We describe the selective cross coupling of methanol and 2-arylethanols using a combination of Ru-MACHO (RuHCl(PNP^Ph)CO) and Shvo’s diruthenium complex as catalysts. The desired domino transformation takes place via so-called borrowing hydrogen methodology, which constitutes an ideal example of green chemistry.

Original language	English
Pages (from-to)	14991-14994
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	95
DOIs	https://doi.org/10.1039/c4cc06933a
State	Published - 4 Nov 2014
Externally published	Yes

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title = "Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock",

abstract = "We describe the selective cross coupling of methanol and 2-arylethanols using a combination of Ru-MACHO (RuHCl(PNPPh)CO) and Shvo{\textquoteright}s diruthenium complex as catalysts. The desired domino transformation takes place via so-called borrowing hydrogen methodology, which constitutes an ideal example of green chemistry.",

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AU - Li, Yang

AU - Li, Haoquan

AU - Junge, Henrik

AU - Beller, Matthias

PY - 2014/11/4

Y1 - 2014/11/4

N2 - We describe the selective cross coupling of methanol and 2-arylethanols using a combination of Ru-MACHO (RuHCl(PNPPh)CO) and Shvo’s diruthenium complex as catalysts. The desired domino transformation takes place via so-called borrowing hydrogen methodology, which constitutes an ideal example of green chemistry.

AB - We describe the selective cross coupling of methanol and 2-arylethanols using a combination of Ru-MACHO (RuHCl(PNPPh)CO) and Shvo’s diruthenium complex as catalysts. The desired domino transformation takes place via so-called borrowing hydrogen methodology, which constitutes an ideal example of green chemistry.

UR - https://www.scopus.com/pages/publications/84908689189

U2 - 10.1039/c4cc06933a

DO - 10.1039/c4cc06933a

M3 - 文章

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SP - 14991

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JO - Chemical Communications

JF - Chemical Communications

IS - 95

ER -

Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock

Abstract

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