Relaxations in heterolanthanide dinuclear single-molecule magnets

Ji Dong Leng; Jun Liang Liu; Yan Zhen Zheng; Liviu Ungur; Liviu F. Chibotaru; Fu Sheng Guo; Ming Liang Tong

doi:10.1039/c2cc37036k

Relaxations in heterolanthanide dinuclear single-molecule magnets

Ji Dong Leng
, Jun Liang Liu
, Yan Zhen Zheng
, Liviu Ungur
, Liviu F. Chibotaru
, Fu Sheng Guo
, Ming Liang Tong

School of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

A heterospin dinuclear complex [Dy_0.87Yb_1.13(H₂cht)₂Cl₄(H₂O)(MeCN)]·;MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy₂ and Yb₂ isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.

Original language	English
Pages (from-to)	158-160
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	2
DOIs	https://doi.org/10.1039/c2cc37036k
State	Published - 2013

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title = "Relaxations in heterolanthanide dinuclear single-molecule magnets",

abstract = "A heterospin dinuclear complex [Dy0.87Yb1.13(H2cht)2Cl4(H2O)(MeCN)]·;MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy2 and Yb2 isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.",

author = "Leng, \{Ji Dong\} and Liu, \{Jun Liang\} and Zheng, \{Yan Zhen\} and Liviu Ungur and Chibotaru, \{Liviu F.\} and Guo, \{Fu Sheng\} and Tong, \{Ming Liang\}",

year = "2013",

doi = "10.1039/c2cc37036k",

language = "英语",

volume = "49",

pages = "158--160",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Relaxations in heterolanthanide dinuclear single-molecule magnets

AU - Leng, Ji Dong

AU - Liu, Jun Liang

AU - Zheng, Yan Zhen

AU - Ungur, Liviu

AU - Chibotaru, Liviu F.

AU - Guo, Fu Sheng

AU - Tong, Ming Liang

PY - 2013

Y1 - 2013

N2 - A heterospin dinuclear complex [Dy0.87Yb1.13(H2cht)2Cl4(H2O)(MeCN)]·;MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy2 and Yb2 isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.

AB - A heterospin dinuclear complex [Dy0.87Yb1.13(H2cht)2Cl4(H2O)(MeCN)]·;MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy2 and Yb2 isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.

UR - https://www.scopus.com/pages/publications/84870513629

U2 - 10.1039/c2cc37036k

DO - 10.1039/c2cc37036k

M3 - 文章

AN - SCOPUS:84870513629

SN - 1359-7345

VL - 49

SP - 158

EP - 160

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

Relaxations in heterolanthanide dinuclear single-molecule magnets

Abstract

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