Quantum Dots Supply Bulk- and Surface-Passivation Agents for Efficient and Stable Perovskite Solar Cells

Xiaopeng Zheng; Joel Troughton; Nicola Gasparini; Yuanbao Lin; Mingyang Wei; Yi Hou; Jiakai Liu; Kepeng Song; Zhaolai Chen; Chen Yang; Bekir Turedi; Abdullah Y. Alsalloum; Jun Pan; Jie Chen; Ayan A. Zhumekenov; Thomas D. Anthopoulos; Yu Han; Derya Baran; Omar F. Mohammed; Edward H. Sargent; Osman M. Bakr

doi:10.1016/j.joule.2019.05.005

Quantum Dots Supply Bulk- and Surface-Passivation Agents for Efficient and Stable Perovskite Solar Cells

Xiaopeng Zheng
, Joel Troughton
, Nicola Gasparini
, Yuanbao Lin
, Mingyang Wei
, Yi Hou
, Jiakai Liu
, Kepeng Song
, Zhaolai Chen
, Chen Yang
, Bekir Turedi
, Abdullah Y. Alsalloum
, Jun Pan
, Jie Chen
, Ayan A. Zhumekenov
, Thomas D. Anthopoulos
, Yu Han
, Derya Baran
, Omar F. Mohammed
, Edward H. Sargent

Osman M. Bakr

King Abdullah University of Science and Technology
University of Toronto

Research output: Contribution to journal › Article › peer-review

259 Scopus citations

Abstract

We report a facile processing strategy that utilizes perovskite quantum dots (QDs) to distribute elemental dopants uniformly across a MAPbI₃ film and anchor ligands to the film's surface—reducing the film's trap-state density and rendering its surface hydrophobic. QD-treated MAPbI₃ films yield solar cells with 21.5% power conversion efficiency (PCE) (versus 18.3% for non-QD-treated) and maintain 80% of their initial PCE under 1-sun continuous illumination for 500 h with improved thermal stability.

Original language	English
Pages (from-to)	1963-1976
Number of pages	14
Journal	Joule
Volume	3
Issue number	8
DOIs	https://doi.org/10.1016/j.joule.2019.05.005
State	Published - 21 Aug 2019
Externally published	Yes

Keywords

doping
nanocrystals
perovskite solar cells
quantum dots
self-assembled monolayer
stability
surface modification

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10.1016/j.joule.2019.05.005

Cite this

Zheng, X., Troughton, J., Gasparini, N., Lin, Y., Wei, M., Hou, Y., Liu, J., Song, K., Chen, Z., Yang, C., Turedi, B., Alsalloum, A. Y., Pan, J., Chen, J., Zhumekenov, A. A., Anthopoulos, T. D., Han, Y., Baran, D., Mohammed, O. F., ... Bakr, O. M. (2019). Quantum Dots Supply Bulk- and Surface-Passivation Agents for Efficient and Stable Perovskite Solar Cells. Joule, 3(8), 1963-1976. https://doi.org/10.1016/j.joule.2019.05.005

@article{c1884d0a35aa4583a89471defa48766e,

title = "Quantum Dots Supply Bulk- and Surface-Passivation Agents for Efficient and Stable Perovskite Solar Cells",

abstract = "We report a facile processing strategy that utilizes perovskite quantum dots (QDs) to distribute elemental dopants uniformly across a MAPbI3 film and anchor ligands to the film's surface{\textemdash}reducing the film's trap-state density and rendering its surface hydrophobic. QD-treated MAPbI3 films yield solar cells with 21.5\% power conversion efficiency (PCE) (versus 18.3\% for non-QD-treated) and maintain 80\% of their initial PCE under 1-sun continuous illumination for 500 h with improved thermal stability.",

keywords = "doping, nanocrystals, perovskite solar cells, quantum dots, self-assembled monolayer, stability, surface modification",

author = "Xiaopeng Zheng and Joel Troughton and Nicola Gasparini and Yuanbao Lin and Mingyang Wei and Yi Hou and Jiakai Liu and Kepeng Song and Zhaolai Chen and Chen Yang and Bekir Turedi and Alsalloum, \{Abdullah Y.\} and Jun Pan and Jie Chen and Zhumekenov, \{Ayan A.\} and Anthopoulos, \{Thomas D.\} and Yu Han and Derya Baran and Mohammed, \{Omar F.\} and Sargent, \{Edward H.\} and Bakr, \{Osman M.\}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Inc.",

year = "2019",

month = aug,

day = "21",

doi = "10.1016/j.joule.2019.05.005",

language = "英语",

volume = "3",

pages = "1963--1976",

journal = "Joule",

issn = "2542-4351",

publisher = "Cell Press",

number = "8",

}

Zheng, X, Troughton, J, Gasparini, N, Lin, Y, Wei, M, Hou, Y, Liu, J, Song, K, Chen, Z, Yang, C, Turedi, B, Alsalloum, AY, Pan, J, Chen, J, Zhumekenov, AA, Anthopoulos, TD, Han, Y, Baran, D, Mohammed, OF, Sargent, EH & Bakr, OM 2019, 'Quantum Dots Supply Bulk- and Surface-Passivation Agents for Efficient and Stable Perovskite Solar Cells', Joule, vol. 3, no. 8, pp. 1963-1976. https://doi.org/10.1016/j.joule.2019.05.005

TY - JOUR

T1 - Quantum Dots Supply Bulk- and Surface-Passivation Agents for Efficient and Stable Perovskite Solar Cells

AU - Zheng, Xiaopeng

AU - Troughton, Joel

AU - Gasparini, Nicola

AU - Lin, Yuanbao

AU - Wei, Mingyang

AU - Hou, Yi

AU - Liu, Jiakai

AU - Song, Kepeng

AU - Chen, Zhaolai

AU - Yang, Chen

AU - Turedi, Bekir

AU - Alsalloum, Abdullah Y.

AU - Pan, Jun

AU - Chen, Jie

AU - Zhumekenov, Ayan A.

AU - Anthopoulos, Thomas D.

AU - Han, Yu

AU - Baran, Derya

AU - Mohammed, Omar F.

AU - Sargent, Edward H.

AU - Bakr, Osman M.

PY - 2019/8/21

Y1 - 2019/8/21

N2 - We report a facile processing strategy that utilizes perovskite quantum dots (QDs) to distribute elemental dopants uniformly across a MAPbI3 film and anchor ligands to the film's surface—reducing the film's trap-state density and rendering its surface hydrophobic. QD-treated MAPbI3 films yield solar cells with 21.5% power conversion efficiency (PCE) (versus 18.3% for non-QD-treated) and maintain 80% of their initial PCE under 1-sun continuous illumination for 500 h with improved thermal stability.

AB - We report a facile processing strategy that utilizes perovskite quantum dots (QDs) to distribute elemental dopants uniformly across a MAPbI3 film and anchor ligands to the film's surface—reducing the film's trap-state density and rendering its surface hydrophobic. QD-treated MAPbI3 films yield solar cells with 21.5% power conversion efficiency (PCE) (versus 18.3% for non-QD-treated) and maintain 80% of their initial PCE under 1-sun continuous illumination for 500 h with improved thermal stability.

KW - doping

KW - nanocrystals

KW - perovskite solar cells

KW - quantum dots

KW - self-assembled monolayer

KW - stability

KW - surface modification

UR - https://www.scopus.com/pages/publications/85070675424

U2 - 10.1016/j.joule.2019.05.005

DO - 10.1016/j.joule.2019.05.005

M3 - 文章

AN - SCOPUS:85070675424

SN - 2542-4351

VL - 3

SP - 1963

EP - 1976

JO - Joule

JF - Joule

IS - 8

ER -

Quantum Dots Supply Bulk- and Surface-Passivation Agents for Efficient and Stable Perovskite Solar Cells

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Keywords

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