Preparation of one polyurethane material based on epoxidation hydroxyl-terminated polybutadiene

Zhao Zhao Deng; Xue Fei Li; Guo Xin Gao; Yuan Suo Zheng

doi:10.7673/j.issn.1006-2793.2014.01.023

Preparation of one polyurethane material based on epoxidation hydroxyl-terminated polybutadiene

Zhao Zhao Deng
, Xue Fei Li
, Guo Xin Gao
, Yuan Suo Zheng

School of Chemistry

Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The polyurethane material based on Epoxidized Hydroxyl-terminated Polybutadiene(EHTPB) was synthesized with N, N-di(2-hydroxypropyl)aniline(Is) as chain extender and toluene diisocyanate(TDI) as a curing agent. The effects of epoxy value of EHTPB, curing time, molar ratio of Is to EHTPB, NCO/OH ratio and filler dosage on the properties of the polyurethane were investigated. The results show that the optimal molar ratio of Is to EHTPB is 1.54 and the best NCO/OH ratio is 2.05. The best amount of catalyst is 0.075%, the filler dosage of ZnO is 4% and SiO₂ is 1.47%. At 70°C, the best cure time is 5 days. Moreover, the mechanical properties of polyurethane material prepared with EHTPB are superior to those of material with HTPB.

Original language	English
Pages (from-to)	118-121
Number of pages	4
Journal	Guti Huojian Jishu/Journal of Solid Rocket Technology
Volume	37
Issue number	1
DOIs	https://doi.org/10.7673/j.issn.1006-2793.2014.01.023
State	Published - 2014

Keywords

EHTPB
HTPB
PU
Tensile strength

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10.7673/j.issn.1006-2793.2014.01.023

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title = "Preparation of one polyurethane material based on epoxidation hydroxyl-terminated polybutadiene",

abstract = "The polyurethane material based on Epoxidized Hydroxyl-terminated Polybutadiene(EHTPB) was synthesized with N, N-di(2-hydroxypropyl)aniline(Is) as chain extender and toluene diisocyanate(TDI) as a curing agent. The effects of epoxy value of EHTPB, curing time, molar ratio of Is to EHTPB, NCO/OH ratio and filler dosage on the properties of the polyurethane were investigated. The results show that the optimal molar ratio of Is to EHTPB is 1.54 and the best NCO/OH ratio is 2.05. The best amount of catalyst is 0.075\%, the filler dosage of ZnO is 4\% and SiO2 is 1.47\%. At 70°C, the best cure time is 5 days. Moreover, the mechanical properties of polyurethane material prepared with EHTPB are superior to those of material with HTPB.",

keywords = "EHTPB, HTPB, PU, Tensile strength",

author = "Deng, \{Zhao Zhao\} and Li, \{Xue Fei\} and Gao, \{Guo Xin\} and Zheng, \{Yuan Suo\}",

year = "2014",

doi = "10.7673/j.issn.1006-2793.2014.01.023",

language = "英语",

volume = "37",

pages = "118--121",

journal = "Guti Huojian Jishu/Journal of Solid Rocket Technology",

issn = "1006-2793",

publisher = "Journal of Solid Rocket Technology",

number = "1",

}

TY - JOUR

T1 - Preparation of one polyurethane material based on epoxidation hydroxyl-terminated polybutadiene

AU - Deng, Zhao Zhao

AU - Li, Xue Fei

AU - Gao, Guo Xin

AU - Zheng, Yuan Suo

PY - 2014

Y1 - 2014

N2 - The polyurethane material based on Epoxidized Hydroxyl-terminated Polybutadiene(EHTPB) was synthesized with N, N-di(2-hydroxypropyl)aniline(Is) as chain extender and toluene diisocyanate(TDI) as a curing agent. The effects of epoxy value of EHTPB, curing time, molar ratio of Is to EHTPB, NCO/OH ratio and filler dosage on the properties of the polyurethane were investigated. The results show that the optimal molar ratio of Is to EHTPB is 1.54 and the best NCO/OH ratio is 2.05. The best amount of catalyst is 0.075%, the filler dosage of ZnO is 4% and SiO2 is 1.47%. At 70°C, the best cure time is 5 days. Moreover, the mechanical properties of polyurethane material prepared with EHTPB are superior to those of material with HTPB.

AB - The polyurethane material based on Epoxidized Hydroxyl-terminated Polybutadiene(EHTPB) was synthesized with N, N-di(2-hydroxypropyl)aniline(Is) as chain extender and toluene diisocyanate(TDI) as a curing agent. The effects of epoxy value of EHTPB, curing time, molar ratio of Is to EHTPB, NCO/OH ratio and filler dosage on the properties of the polyurethane were investigated. The results show that the optimal molar ratio of Is to EHTPB is 1.54 and the best NCO/OH ratio is 2.05. The best amount of catalyst is 0.075%, the filler dosage of ZnO is 4% and SiO2 is 1.47%. At 70°C, the best cure time is 5 days. Moreover, the mechanical properties of polyurethane material prepared with EHTPB are superior to those of material with HTPB.

KW - EHTPB

KW - HTPB

KW - PU

KW - Tensile strength

UR - https://www.scopus.com/pages/publications/84897138508

U2 - 10.7673/j.issn.1006-2793.2014.01.023

DO - 10.7673/j.issn.1006-2793.2014.01.023

M3 - 文章

AN - SCOPUS:84897138508

SN - 1006-2793

VL - 37

SP - 118

EP - 121

JO - Guti Huojian Jishu/Journal of Solid Rocket Technology

JF - Guti Huojian Jishu/Journal of Solid Rocket Technology

IS - 1

ER -

Preparation of one polyurethane material based on epoxidation hydroxyl-terminated polybutadiene

Abstract

Keywords

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