POSS-based Diblock Fluoropolymer for Self-assembled Hydrophobic Coatings

Aizhao Pan; Ling He; Liang Wang; Na Xi

doi:10.1016/j.matpr.2016.01.077

POSS-based Diblock Fluoropolymer for Self-assembled Hydrophobic Coatings

Aizhao Pan
, Ling He
, Liang Wang
, Na Xi

School of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Linear/star-shaped polyhedral oligomeric silsesquioxane (POSS)-based fluorinated diblock copolymers are synthesized by octakis(dibromoethyl)-POSS (POSS-(Br)₁₆) and aminopropylisobutyl-POSS (ap-POSS) initiating methylmethacrylate (MMA) and dodecafluoroheptylmethacrylate (DFHM), respectively. The effect of solvents on their self-assembled micelles, surface wetability and viscoelasticity of casted films, and the hydrophobic application are characterized. In THF, CHCl₃ and dimethyl carbonate (DMC) solutions, the self-assembled micelles of star-shaped s-POSS-(PMMA-b-PDFHM)₁₆ are larger than linear-shaped ap-POSS-PMMA-b-PDFHM. CHCl₃-casted surface gains the highest roughness, fluoride content, water contact angles, but the lowest water adsorption and viscoelasticity. CHCl₃-micelles exhibit superhydrophobicity to stone and cotton fiber substrates. Therefore, POSS-based fluoropolymer is hoped to act as hydrophobic coatings.

Original language	English
Pages (from-to)	325-334
Number of pages	10
Journal	Materials Today: Proceedings
Volume	3
Issue number	2
DOIs	https://doi.org/10.1016/j.matpr.2016.01.077
State	Published - 2016

Keywords

Hydrophobic coatings
POSS-based fluoropolymer
Self-assembled micelles
Solvent effects
Star/linear-shaped blockpolymer
Surface wetability and viscoelasticity

Access to Document

10.1016/j.matpr.2016.01.077

Cite this

@article{a80108ad8e6d4f7db9f512cc77f8c2e5,

title = "POSS-based Diblock Fluoropolymer for Self-assembled Hydrophobic Coatings",

abstract = "Linear/star-shaped polyhedral oligomeric silsesquioxane (POSS)-based fluorinated diblock copolymers are synthesized by octakis(dibromoethyl)-POSS (POSS-(Br)16) and aminopropylisobutyl-POSS (ap-POSS) initiating methylmethacrylate (MMA) and dodecafluoroheptylmethacrylate (DFHM), respectively. The effect of solvents on their self-assembled micelles, surface wetability and viscoelasticity of casted films, and the hydrophobic application are characterized. In THF, CHCl3 and dimethyl carbonate (DMC) solutions, the self-assembled micelles of star-shaped s-POSS-(PMMA-b-PDFHM)16 are larger than linear-shaped ap-POSS-PMMA-b-PDFHM. CHCl3-casted surface gains the highest roughness, fluoride content, water contact angles, but the lowest water adsorption and viscoelasticity. CHCl3-micelles exhibit superhydrophobicity to stone and cotton fiber substrates. Therefore, POSS-based fluoropolymer is hoped to act as hydrophobic coatings.",

keywords = "Hydrophobic coatings, POSS-based fluoropolymer, Self-assembled micelles, Solvent effects, Star/linear-shaped blockpolymer, Surface wetability and viscoelasticity",

author = "Aizhao Pan and Ling He and Liang Wang and Na Xi",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier Ltd.",

year = "2016",

doi = "10.1016/j.matpr.2016.01.077",

language = "英语",

volume = "3",

pages = "325--334",

journal = "Materials Today: Proceedings",

issn = "2214-7853",

publisher = "Elsevier Ltd",

number = "2",

}

TY - JOUR

T1 - POSS-based Diblock Fluoropolymer for Self-assembled Hydrophobic Coatings

AU - Pan, Aizhao

AU - He, Ling

AU - Wang, Liang

AU - Xi, Na

PY - 2016

Y1 - 2016

N2 - Linear/star-shaped polyhedral oligomeric silsesquioxane (POSS)-based fluorinated diblock copolymers are synthesized by octakis(dibromoethyl)-POSS (POSS-(Br)16) and aminopropylisobutyl-POSS (ap-POSS) initiating methylmethacrylate (MMA) and dodecafluoroheptylmethacrylate (DFHM), respectively. The effect of solvents on their self-assembled micelles, surface wetability and viscoelasticity of casted films, and the hydrophobic application are characterized. In THF, CHCl3 and dimethyl carbonate (DMC) solutions, the self-assembled micelles of star-shaped s-POSS-(PMMA-b-PDFHM)16 are larger than linear-shaped ap-POSS-PMMA-b-PDFHM. CHCl3-casted surface gains the highest roughness, fluoride content, water contact angles, but the lowest water adsorption and viscoelasticity. CHCl3-micelles exhibit superhydrophobicity to stone and cotton fiber substrates. Therefore, POSS-based fluoropolymer is hoped to act as hydrophobic coatings.

AB - Linear/star-shaped polyhedral oligomeric silsesquioxane (POSS)-based fluorinated diblock copolymers are synthesized by octakis(dibromoethyl)-POSS (POSS-(Br)16) and aminopropylisobutyl-POSS (ap-POSS) initiating methylmethacrylate (MMA) and dodecafluoroheptylmethacrylate (DFHM), respectively. The effect of solvents on their self-assembled micelles, surface wetability and viscoelasticity of casted films, and the hydrophobic application are characterized. In THF, CHCl3 and dimethyl carbonate (DMC) solutions, the self-assembled micelles of star-shaped s-POSS-(PMMA-b-PDFHM)16 are larger than linear-shaped ap-POSS-PMMA-b-PDFHM. CHCl3-casted surface gains the highest roughness, fluoride content, water contact angles, but the lowest water adsorption and viscoelasticity. CHCl3-micelles exhibit superhydrophobicity to stone and cotton fiber substrates. Therefore, POSS-based fluoropolymer is hoped to act as hydrophobic coatings.

KW - Hydrophobic coatings

KW - POSS-based fluoropolymer

KW - Self-assembled micelles

KW - Solvent effects

KW - Star/linear-shaped blockpolymer

KW - Surface wetability and viscoelasticity

UR - https://www.scopus.com/pages/publications/84963632000

U2 - 10.1016/j.matpr.2016.01.077

DO - 10.1016/j.matpr.2016.01.077

M3 - 文章

AN - SCOPUS:84963632000

SN - 2214-7853

VL - 3

SP - 325

EP - 334

JO - Materials Today: Proceedings

JF - Materials Today: Proceedings

IS - 2

ER -

POSS-based Diblock Fluoropolymer for Self-assembled Hydrophobic Coatings

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this