Poly(trimethylene monothiocarbonate) from the Alternating Copolymerization of COS and Oxetane: A Semicrystalline Copolymer

Hai Lin Wu; Jia Liang Yang; Ming Luo; Rui Yang Wang; Jun Ting Xu; Bin Yang Du; Xing Hong Zhang; Donald J. Darensbourg

doi:10.1021/acs.macromol.6b02285

Poly(trimethylene monothiocarbonate) from the Alternating Copolymerization of COS and Oxetane: A Semicrystalline Copolymer

Hai Lin Wu
, Jia Liang Yang
, Ming Luo
, Rui Yang Wang
, Jun Ting Xu
, Bin Yang Du
, Xing Hong Zhang
, Donald J. Darensbourg

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

A semicrystalline poly(trimethylene monothiocarbonate) (PTMMTC) has been synthesized via the selective and alternating copolymerization of carbonyl sulfide and oxetane. This reaction was catalyzed by (salen)CrCl accompanied by organic bases over a wide range of temperatures from 40 to 130 °C. PTMMTC is shown to exhibit similar crystallization behavior to high-density polyethylene (HDPE), i.e., being spherulite and possessing melting temperatures (T_m) up to 127.5 °C and a degree of crystallinity (X_c) of up to 71%. Moreover, PTMMTC has a wide processing temperature window of ca. 100 °C.

Original language	English
Pages (from-to)	8863-8868
Number of pages	6
Journal	Macromolecules
Volume	49
Issue number	23
DOIs	https://doi.org/10.1021/acs.macromol.6b02285
State	Published - 13 Dec 2016
Externally published	Yes

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title = "Poly(trimethylene monothiocarbonate) from the Alternating Copolymerization of COS and Oxetane: A Semicrystalline Copolymer",

abstract = "A semicrystalline poly(trimethylene monothiocarbonate) (PTMMTC) has been synthesized via the selective and alternating copolymerization of carbonyl sulfide and oxetane. This reaction was catalyzed by (salen)CrCl accompanied by organic bases over a wide range of temperatures from 40 to 130 °C. PTMMTC is shown to exhibit similar crystallization behavior to high-density polyethylene (HDPE), i.e., being spherulite and possessing melting temperatures (Tm) up to 127.5 °C and a degree of crystallinity (Xc) of up to 71\%. Moreover, PTMMTC has a wide processing temperature window of ca. 100 °C.",

author = "Wu, \{Hai Lin\} and Yang, \{Jia Liang\} and Ming Luo and Wang, \{Rui Yang\} and Xu, \{Jun Ting\} and Du, \{Bin Yang\} and Zhang, \{Xing Hong\} and Darensbourg, \{Donald J.\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = dec,

day = "13",

doi = "10.1021/acs.macromol.6b02285",

language = "英语",

volume = "49",

pages = "8863--8868",

journal = "Macromolecules",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Poly(trimethylene monothiocarbonate) from the Alternating Copolymerization of COS and Oxetane

T2 - A Semicrystalline Copolymer

AU - Wu, Hai Lin

AU - Yang, Jia Liang

AU - Luo, Ming

AU - Wang, Rui Yang

AU - Xu, Jun Ting

AU - Du, Bin Yang

AU - Zhang, Xing Hong

AU - Darensbourg, Donald J.

PY - 2016/12/13

Y1 - 2016/12/13

N2 - A semicrystalline poly(trimethylene monothiocarbonate) (PTMMTC) has been synthesized via the selective and alternating copolymerization of carbonyl sulfide and oxetane. This reaction was catalyzed by (salen)CrCl accompanied by organic bases over a wide range of temperatures from 40 to 130 °C. PTMMTC is shown to exhibit similar crystallization behavior to high-density polyethylene (HDPE), i.e., being spherulite and possessing melting temperatures (Tm) up to 127.5 °C and a degree of crystallinity (Xc) of up to 71%. Moreover, PTMMTC has a wide processing temperature window of ca. 100 °C.

AB - A semicrystalline poly(trimethylene monothiocarbonate) (PTMMTC) has been synthesized via the selective and alternating copolymerization of carbonyl sulfide and oxetane. This reaction was catalyzed by (salen)CrCl accompanied by organic bases over a wide range of temperatures from 40 to 130 °C. PTMMTC is shown to exhibit similar crystallization behavior to high-density polyethylene (HDPE), i.e., being spherulite and possessing melting temperatures (Tm) up to 127.5 °C and a degree of crystallinity (Xc) of up to 71%. Moreover, PTMMTC has a wide processing temperature window of ca. 100 °C.

UR - https://www.scopus.com/pages/publications/85006305813

U2 - 10.1021/acs.macromol.6b02285

DO - 10.1021/acs.macromol.6b02285

M3 - 文章

AN - SCOPUS:85006305813

SN - 0024-9297

VL - 49

SP - 8863

EP - 8868

JO - Macromolecules

JF - Macromolecules

IS - 23

ER -

Poly(trimethylene monothiocarbonate) from the Alternating Copolymerization of COS and Oxetane: A Semicrystalline Copolymer

Abstract

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