Polarization- And Strain-Mediated Control of Negative Thermal Expansion and Ferroelasticity in BiInO3-BiZn1/2Ti1/2O3

Takumi Nishikubo; Takahiro Ogata; Lalitha Kodumudi Venkataraman; Daniel Isaia; Zhao Pan; Yuki Sakai; Lei Hu; Shogo Kawaguchi; Akihiko Machida; Tetsu Watanuki; Hongwu Yu; Yoichi Okimoto; Shin Ya Koshihara; Shigeo Mori; Jürgen Rödel; Masaki Azuma

doi:10.1021/acs.chemmater.0c04049

Polarization- And Strain-Mediated Control of Negative Thermal Expansion and Ferroelasticity in BiInO₃-BiZn_1/2Ti_1/2O₃

Takumi Nishikubo
, Takahiro Ogata
, Lalitha Kodumudi Venkataraman
, Daniel Isaia
, Zhao Pan
, Yuki Sakai
, Lei Hu
, Shogo Kawaguchi
, Akihiko Machida
, Tetsu Watanuki
, Hongwu Yu
, Yoichi Okimoto
, Shin Ya Koshihara
, Shigeo Mori
, Jürgen Rödel
, Masaki Azuma

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A solid solution between polar perovskite oxides BiInO3 and BiZn1/2Ti1/2O3 with the atomic displacement of Bi3+ and B-site (In and Zn1/2Ti1/2) as the origin of spontaneous electric polarization was investigated. Polar orthorhombic to nonpolar orthorhombic transition accompanied by negative thermal expansion (NTE) with constant volume shrinkage was observed for x ≤ 0.3 in BiIn1-xZnx/2Tix/2O3. A relative shift of electrical polarization from A-site Bi3+ to B-site ions reduced the transition temperature and enabled NTE in a wide temperature range with suppressed temperature hysteresis. In addition, new LiNbO3-type phases were found for 0.4 ≤ x ≤ 0.8 with ferroelastic and piezoelectric behaviors, featuring a very high switching strain and demonstrating the potential for enhanced domain wall mobility.

Original language	English
Pages (from-to)	1498-1505
Number of pages	8
Journal	Chemistry of Materials
Volume	33
Issue number	4
DOIs	https://doi.org/10.1021/acs.chemmater.0c04049
State	Published - 23 Feb 2021
Externally published	Yes

Access to Document

10.1021/acs.chemmater.0c04049

Cite this

Nishikubo, T., Ogata, T., Venkataraman, L. K., Isaia, D., Pan, Z., Sakai, Y., Hu, L., Kawaguchi, S., Machida, A., Watanuki, T., Yu, H., Okimoto, Y., Koshihara, S. Y., Mori, S., Rödel, J., & Azuma, M. (2021). Polarization- And Strain-Mediated Control of Negative Thermal Expansion and Ferroelasticity in BiInO₃-BiZn_1/2Ti_1/2O₃. Chemistry of Materials, 33(4), 1498-1505. https://doi.org/10.1021/acs.chemmater.0c04049

@article{e0d523141e3c47b692fb9834e710ac6f,

title = "Polarization- And Strain-Mediated Control of Negative Thermal Expansion and Ferroelasticity in BiInO3-BiZn1/2Ti1/2O3",

abstract = "A solid solution between polar perovskite oxides BiInO3 and BiZn1/2Ti1/2O3 with the atomic displacement of Bi3+ and B-site (In and Zn1/2Ti1/2) as the origin of spontaneous electric polarization was investigated. Polar orthorhombic to nonpolar orthorhombic transition accompanied by negative thermal expansion (NTE) with constant volume shrinkage was observed for x ≤ 0.3 in BiIn1-xZnx/2Tix/2O3. A relative shift of electrical polarization from A-site Bi3+ to B-site ions reduced the transition temperature and enabled NTE in a wide temperature range with suppressed temperature hysteresis. In addition, new LiNbO3-type phases were found for 0.4 ≤ x ≤ 0.8 with ferroelastic and piezoelectric behaviors, featuring a very high switching strain and demonstrating the potential for enhanced domain wall mobility.",

author = "Takumi Nishikubo and Takahiro Ogata and Venkataraman, \{Lalitha Kodumudi\} and Daniel Isaia and Zhao Pan and Yuki Sakai and Lei Hu and Shogo Kawaguchi and Akihiko Machida and Tetsu Watanuki and Hongwu Yu and Yoichi Okimoto and Koshihara, \{Shin Ya\} and Shigeo Mori and J{\"u}rgen R{\"o}del and Masaki Azuma",

note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society.",

year = "2021",

month = feb,

day = "23",

doi = "10.1021/acs.chemmater.0c04049",

language = "英语",

volume = "33",

pages = "1498--1505",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "4",

}

Nishikubo, T, Ogata, T, Venkataraman, LK, Isaia, D, Pan, Z, Sakai, Y, Hu, L, Kawaguchi, S, Machida, A, Watanuki, T, Yu, H, Okimoto, Y, Koshihara, SY, Mori, S, Rödel, J & Azuma, M 2021, 'Polarization- And Strain-Mediated Control of Negative Thermal Expansion and Ferroelasticity in BiInO₃-BiZn_1/2Ti_1/2O₃', Chemistry of Materials, vol. 33, no. 4, pp. 1498-1505. https://doi.org/10.1021/acs.chemmater.0c04049

TY - JOUR

T1 - Polarization- And Strain-Mediated Control of Negative Thermal Expansion and Ferroelasticity in BiInO3-BiZn1/2Ti1/2O3

AU - Nishikubo, Takumi

AU - Ogata, Takahiro

AU - Venkataraman, Lalitha Kodumudi

AU - Isaia, Daniel

AU - Pan, Zhao

AU - Sakai, Yuki

AU - Hu, Lei

AU - Kawaguchi, Shogo

AU - Machida, Akihiko

AU - Watanuki, Tetsu

AU - Yu, Hongwu

AU - Okimoto, Yoichi

AU - Koshihara, Shin Ya

AU - Mori, Shigeo

AU - Rödel, Jürgen

AU - Azuma, Masaki

PY - 2021/2/23

Y1 - 2021/2/23

N2 - A solid solution between polar perovskite oxides BiInO3 and BiZn1/2Ti1/2O3 with the atomic displacement of Bi3+ and B-site (In and Zn1/2Ti1/2) as the origin of spontaneous electric polarization was investigated. Polar orthorhombic to nonpolar orthorhombic transition accompanied by negative thermal expansion (NTE) with constant volume shrinkage was observed for x ≤ 0.3 in BiIn1-xZnx/2Tix/2O3. A relative shift of electrical polarization from A-site Bi3+ to B-site ions reduced the transition temperature and enabled NTE in a wide temperature range with suppressed temperature hysteresis. In addition, new LiNbO3-type phases were found for 0.4 ≤ x ≤ 0.8 with ferroelastic and piezoelectric behaviors, featuring a very high switching strain and demonstrating the potential for enhanced domain wall mobility.

AB - A solid solution between polar perovskite oxides BiInO3 and BiZn1/2Ti1/2O3 with the atomic displacement of Bi3+ and B-site (In and Zn1/2Ti1/2) as the origin of spontaneous electric polarization was investigated. Polar orthorhombic to nonpolar orthorhombic transition accompanied by negative thermal expansion (NTE) with constant volume shrinkage was observed for x ≤ 0.3 in BiIn1-xZnx/2Tix/2O3. A relative shift of electrical polarization from A-site Bi3+ to B-site ions reduced the transition temperature and enabled NTE in a wide temperature range with suppressed temperature hysteresis. In addition, new LiNbO3-type phases were found for 0.4 ≤ x ≤ 0.8 with ferroelastic and piezoelectric behaviors, featuring a very high switching strain and demonstrating the potential for enhanced domain wall mobility.

UR - https://www.scopus.com/pages/publications/85099929091

U2 - 10.1021/acs.chemmater.0c04049

DO - 10.1021/acs.chemmater.0c04049

M3 - 文章

AN - SCOPUS:85099929091

SN - 0897-4756

VL - 33

SP - 1498

EP - 1505

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 4

ER -

Polarization- And Strain-Mediated Control of Negative Thermal Expansion and Ferroelasticity in BiInO₃-BiZn_1/2Ti_1/2O₃

Abstract

Access to Document

Other files and links

Fingerprint

Cite this