Plasma deposition of polymer electrolyte membrane for proton exchange membrane fuel cell (PEMFC) applications

Zhongqing Jiang; Zhong Jie Jiang; Xinyao Yu; Yuedong Meng; Jiangang Li

doi:10.1016/j.surfcoat.2010.07.085

Plasma deposition of polymer electrolyte membrane for proton exchange membrane fuel cell (PEMFC) applications

Zhongqing Jiang
, Zhong Jie Jiang
, Xinyao Yu
, Yuedong Meng
, Jiangang Li

School of Electrical Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Sulfonated 'Nafion-like' plasma polymerized membranes were synthesized by plasma polymerization of a mixture of styrene and trifluoromethane sulfonic acid monomers in a low-frequency after-glow capacitively coupled plasma (CCP) discharge reactor. The synthesized plasma polymerized membranes are flat and uniform with a few microns thickness. Their structure detected by Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy is very rich with sulfonic acid groups (up to 3at.%). The proton transport number and ion exchange capacity were investigated in details. The results are compared with that of a commercial available Nafion^® 117.

Original language	English
Pages (from-to)	S231-S235
Journal	Surface and Coatings Technology
Volume	205
Issue number	SUPPL. 1
DOIs	https://doi.org/10.1016/j.surfcoat.2010.07.085
State	Published - 25 Dec 2010

Keywords

Ion exchange capacity
Plasma polymerized membranes
Proton transport number
Styrene
Trifluoromethane sulfonic acid

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10.1016/j.surfcoat.2010.07.085

Cite this

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title = "Plasma deposition of polymer electrolyte membrane for proton exchange membrane fuel cell (PEMFC) applications",

abstract = "Sulfonated 'Nafion-like' plasma polymerized membranes were synthesized by plasma polymerization of a mixture of styrene and trifluoromethane sulfonic acid monomers in a low-frequency after-glow capacitively coupled plasma (CCP) discharge reactor. The synthesized plasma polymerized membranes are flat and uniform with a few microns thickness. Their structure detected by Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy is very rich with sulfonic acid groups (up to 3at.\%). The proton transport number and ion exchange capacity were investigated in details. The results are compared with that of a commercial available Nafion{\textregistered} 117.",

keywords = "Ion exchange capacity, Plasma polymerized membranes, Proton transport number, Styrene, Trifluoromethane sulfonic acid",

author = "Zhongqing Jiang and Jiang, \{Zhong Jie\} and Xinyao Yu and Yuedong Meng and Jiangang Li",

year = "2010",

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doi = "10.1016/j.surfcoat.2010.07.085",

language = "英语",

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journal = "Surface and Coatings Technology",

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T1 - Plasma deposition of polymer electrolyte membrane for proton exchange membrane fuel cell (PEMFC) applications

AU - Jiang, Zhongqing

AU - Jiang, Zhong Jie

AU - Yu, Xinyao

AU - Meng, Yuedong

AU - Li, Jiangang

PY - 2010/12/25

Y1 - 2010/12/25

N2 - Sulfonated 'Nafion-like' plasma polymerized membranes were synthesized by plasma polymerization of a mixture of styrene and trifluoromethane sulfonic acid monomers in a low-frequency after-glow capacitively coupled plasma (CCP) discharge reactor. The synthesized plasma polymerized membranes are flat and uniform with a few microns thickness. Their structure detected by Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy is very rich with sulfonic acid groups (up to 3at.%). The proton transport number and ion exchange capacity were investigated in details. The results are compared with that of a commercial available Nafion® 117.

AB - Sulfonated 'Nafion-like' plasma polymerized membranes were synthesized by plasma polymerization of a mixture of styrene and trifluoromethane sulfonic acid monomers in a low-frequency after-glow capacitively coupled plasma (CCP) discharge reactor. The synthesized plasma polymerized membranes are flat and uniform with a few microns thickness. Their structure detected by Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy is very rich with sulfonic acid groups (up to 3at.%). The proton transport number and ion exchange capacity were investigated in details. The results are compared with that of a commercial available Nafion® 117.

KW - Ion exchange capacity

KW - Plasma polymerized membranes

KW - Proton transport number

KW - Styrene

KW - Trifluoromethane sulfonic acid

UR - https://www.scopus.com/pages/publications/78649967357

U2 - 10.1016/j.surfcoat.2010.07.085

DO - 10.1016/j.surfcoat.2010.07.085

M3 - 文章

AN - SCOPUS:78649967357

SN - 0257-8972

VL - 205

SP - S231-S235

JO - Surface and Coatings Technology

JF - Surface and Coatings Technology

IS - SUPPL. 1

ER -

Plasma deposition of polymer electrolyte membrane for proton exchange membrane fuel cell (PEMFC) applications

Abstract

Keywords

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