Photochemical-controlled switching based on azobenzene monolayer modified silicon (111) surface

Yongqiang Wen; Wenhui Yi; Lingjie Meng; Min Feng; Guiyuan Jiang; Wenfang Yuan; Yuqi Zhang; Hongjun Gao; Lei Jiang; Yanlin Song

doi:10.1021/jp044256t

Photochemical-controlled switching based on azobenzene monolayer modified silicon (111) surface

Yongqiang Wen
, Wenhui Yi
, Lingjie Meng
, Min Feng
, Guiyuan Jiang
, Wenfang Yuan
, Yuqi Zhang
, Hongjun Gao
, Lei Jiang
, Yanlin Song

School of Chemistry

CAS - Institute of Chemistry
Xi'an Jiaotong University
CAS - Institute of Physics

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

Azobenzene-containing compounds were covalently attached onto Si(111) surfaces via Si-O linkages using a two-step procedure. The modified Si(111) surfaces were characterized by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) spectroscopy measurements. The monolayer surface showed preferably chemical stability. Switchable photoisomerizability of azobenzéne molecules on these modified surfaces was observed in response to alternating UV and visible light exposure. The measured conductivity showed distinct difference with trans and cis forms of azobenzene compounds on as-modified Si(111) surfaces.

Original language	English
Pages (from-to)	14465-14468
Number of pages	4
Journal	Journal of Physical Chemistry B
Volume	109
Issue number	30
DOIs	https://doi.org/10.1021/jp044256t
State	Published - 4 Aug 2005

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10.1021/jp044256t

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title = "Photochemical-controlled switching based on azobenzene monolayer modified silicon (111) surface",

abstract = "Azobenzene-containing compounds were covalently attached onto Si(111) surfaces via Si-O linkages using a two-step procedure. The modified Si(111) surfaces were characterized by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) spectroscopy measurements. The monolayer surface showed preferably chemical stability. Switchable photoisomerizability of azobenz{\'e}ne molecules on these modified surfaces was observed in response to alternating UV and visible light exposure. The measured conductivity showed distinct difference with trans and cis forms of azobenzene compounds on as-modified Si(111) surfaces.",

author = "Yongqiang Wen and Wenhui Yi and Lingjie Meng and Min Feng and Guiyuan Jiang and Wenfang Yuan and Yuqi Zhang and Hongjun Gao and Lei Jiang and Yanlin Song",

year = "2005",

month = aug,

day = "4",

doi = "10.1021/jp044256t",

language = "英语",

volume = "109",

pages = "14465--14468",

journal = "Journal of Physical Chemistry B",

issn = "1520-6106",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Photochemical-controlled switching based on azobenzene monolayer modified silicon (111) surface

AU - Wen, Yongqiang

AU - Yi, Wenhui

AU - Meng, Lingjie

AU - Feng, Min

AU - Jiang, Guiyuan

AU - Yuan, Wenfang

AU - Zhang, Yuqi

AU - Gao, Hongjun

AU - Jiang, Lei

AU - Song, Yanlin

PY - 2005/8/4

Y1 - 2005/8/4

N2 - Azobenzene-containing compounds were covalently attached onto Si(111) surfaces via Si-O linkages using a two-step procedure. The modified Si(111) surfaces were characterized by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) spectroscopy measurements. The monolayer surface showed preferably chemical stability. Switchable photoisomerizability of azobenzéne molecules on these modified surfaces was observed in response to alternating UV and visible light exposure. The measured conductivity showed distinct difference with trans and cis forms of azobenzene compounds on as-modified Si(111) surfaces.

AB - Azobenzene-containing compounds were covalently attached onto Si(111) surfaces via Si-O linkages using a two-step procedure. The modified Si(111) surfaces were characterized by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) spectroscopy measurements. The monolayer surface showed preferably chemical stability. Switchable photoisomerizability of azobenzéne molecules on these modified surfaces was observed in response to alternating UV and visible light exposure. The measured conductivity showed distinct difference with trans and cis forms of azobenzene compounds on as-modified Si(111) surfaces.

UR - https://www.scopus.com/pages/publications/23844533814

U2 - 10.1021/jp044256t

DO - 10.1021/jp044256t

M3 - 文章

AN - SCOPUS:23844533814

SN - 1520-6106

VL - 109

SP - 14465

EP - 14468

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 30

ER -

Photochemical-controlled switching based on azobenzene monolayer modified silicon (111) surface

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