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Phosphonates as ligands in Co-Cr heterometallic clusters

  • Yan Zhen Zheng
  • , Barbara A. Breeze
  • , Grigore A. Timco
  • , Floriana Tuna
  • , Richard E.P. Winpenny
  • University of Manchester

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Two new Co(ii)-Cr(iii) phosphonate clusters with [CoII 4CrIII4] and [CoII 8CrIII4] cores have been synthesized by a displacement reaction from a pre-formed heterometallic carboxylate cage. Magnetic studies show overall antiferromagnetic interactions are present in these clusters.

Original languageEnglish
Pages (from-to)6175-6177
Number of pages3
JournalDalton Transactions
Volume39
Issue number27
DOIs
StatePublished - 2010
Externally publishedYes

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