Phonon Dressing Induced Dipole Moment Alignment of Nonpolar Ions

We report phonon dressing-induced dipole moment alignment of nonpolar ions. Out-of-phase Fluorescence (FL) and in-phase Spontaneous Four-wave Mixing (SFWM) peak alignment are exhibited owing to dressing-assisted fine structure and hyperfine structure crystal field quantization, whereas FL and SFWM dip alignment result from fine structure crystal field and dressing quantization. Moreover, a constant alignment is maintained by adjusting two-dimensional parameters at certain conditions due to level angular momentum quantization. Such investigation can potentially apply to fine/hyperfine structure alignment of nonpolar ions and spectra homogenizers.