Phase distribution and corresponding piezoelectric responses in a morphotropic phase boundary Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystal revealed by confocal Raman spectroscopy and piezo-response force microscopy

Qingyuan Hu; D. O. Alikin; P. S. Zelenovskiy; A. D. Ushakov; D. S. Chezganov; Jihong Bian; Ye Zhao; Ye Tian; Yongyong Zhuang; Jinglei Li; Li Jin; Zhuo Xu; Vladimir Ya. Shur; Xiaoyong Wei

doi:10.1016/j.jeurceramsoc.2019.05.046

Phase distribution and corresponding piezoelectric responses in a morphotropic phase boundary Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystal revealed by confocal Raman spectroscopy and piezo-response force microscopy

Qingyuan Hu
, D. O. Alikin
, P. S. Zelenovskiy
, A. D. Ushakov
, D. S. Chezganov
, Jihong Bian
, Ye Zhao
, Ye Tian
, Yongyong Zhuang
, Jinglei Li
, Li Jin
, Zhuo Xu
, Vladimir Ya. Shur
, Xiaoyong Wei

Faculty of Electronic and Information Engineering

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Pb(Mg_1/3Nb_2/3)O₃-xPbTiO₃ (PMN-xPT) single crystals exhibit ultrahigh piezoelectric property and have already been applied in various industrial fields. Here, spatial distribution of coexistent phases and corresponding local piezoelectric responses in a morphotropic phase boundary (MPB) PMN-xPT single crystal are thoroughly investigated by confocal Raman spectroscopy coupled with piezo-response force microscopy (PFM). Different from previous studies on MPB crystals, spatial distribution of coexistent phases is exhibited intuitively in an image obtained by confocal Raman mapping. Via in-situ PFM measurements, domain morphology of each coexistent phase is observed. Moreover, local piezoelectric responses of each coexistent phase are obtained by switching spectroscopy PFM measurements, indicating that Ma and Mc phases behave like PNRs and polar matrix in PMN-xPT crystals Our work clarifies the contribution from different phases to the giant piezoelectric performance, which can deepen the understanding on the ultrahigh piezoelectricity in PMN-xPT crystals and provide the key point for developing novel high piezoelectricity materials.

Original language	English
Pages (from-to)	4131-4138
Number of pages	8
Journal	Journal of the European Ceramic Society
Volume	39
Issue number	14
DOIs	https://doi.org/10.1016/j.jeurceramsoc.2019.05.046
State	Published - Nov 2019

Keywords

Confocal Raman spectroscopy
Heterogeneous structure
Local piezo-responses
PFM
Relaxor ferroelectric single crystal

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Hu, Q., Alikin, D. O., Zelenovskiy, P. S., Ushakov, A. D., Chezganov, D. S., Bian, J., Zhao, Y., Tian, Y., Zhuang, Y., Li, J., Jin, L., Xu, Z., Ya. Shur, V., & Wei, X. (2019). Phase distribution and corresponding piezoelectric responses in a morphotropic phase boundary Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystal revealed by confocal Raman spectroscopy and piezo-response force microscopy. Journal of the European Ceramic Society, 39(14), 4131-4138. https://doi.org/10.1016/j.jeurceramsoc.2019.05.046

@article{c9a9516873104f2ba3c6dd7ab43b0ded,

title = "Phase distribution and corresponding piezoelectric responses in a morphotropic phase boundary Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystal revealed by confocal Raman spectroscopy and piezo-response force microscopy",

abstract = "Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT) single crystals exhibit ultrahigh piezoelectric property and have already been applied in various industrial fields. Here, spatial distribution of coexistent phases and corresponding local piezoelectric responses in a morphotropic phase boundary (MPB) PMN-xPT single crystal are thoroughly investigated by confocal Raman spectroscopy coupled with piezo-response force microscopy (PFM). Different from previous studies on MPB crystals, spatial distribution of coexistent phases is exhibited intuitively in an image obtained by confocal Raman mapping. Via in-situ PFM measurements, domain morphology of each coexistent phase is observed. Moreover, local piezoelectric responses of each coexistent phase are obtained by switching spectroscopy PFM measurements, indicating that Ma and Mc phases behave like PNRs and polar matrix in PMN-xPT crystals Our work clarifies the contribution from different phases to the giant piezoelectric performance, which can deepen the understanding on the ultrahigh piezoelectricity in PMN-xPT crystals and provide the key point for developing novel high piezoelectricity materials.",

keywords = "Confocal Raman spectroscopy, Heterogeneous structure, Local piezo-responses, PFM, Relaxor ferroelectric single crystal",

author = "Qingyuan Hu and Alikin, \{D. O.\} and Zelenovskiy, \{P. S.\} and Ushakov, \{A. D.\} and Chezganov, \{D. S.\} and Jihong Bian and Ye Zhao and Ye Tian and Yongyong Zhuang and Jinglei Li and Li Jin and Zhuo Xu and \{Ya. Shur\}, Vladimir and Xiaoyong Wei",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2019",

month = nov,

doi = "10.1016/j.jeurceramsoc.2019.05.046",

language = "英语",

volume = "39",

pages = "4131--4138",

journal = "Journal of the European Ceramic Society",

issn = "0955-2219",

publisher = "Elsevier B.V.",

number = "14",

}

Hu, Q, Alikin, DO, Zelenovskiy, PS, Ushakov, AD, Chezganov, DS, Bian, J, Zhao, Y, Tian, Y, Zhuang, Y , Li, J , Jin, L , Xu, Z, Ya. Shur, V & Wei, X 2019, 'Phase distribution and corresponding piezoelectric responses in a morphotropic phase boundary Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystal revealed by confocal Raman spectroscopy and piezo-response force microscopy', Journal of the European Ceramic Society, vol. 39, no. 14, pp. 4131-4138. https://doi.org/10.1016/j.jeurceramsoc.2019.05.046

Phase distribution and corresponding piezoelectric responses in a morphotropic phase boundary Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystal revealed by confocal Raman spectroscopy and piezo-response force microscopy. / Hu, Qingyuan; Alikin, D. O.; Zelenovskiy, P. S. et al.
In: Journal of the European Ceramic Society, Vol. 39, No. 14, 11.2019, p. 4131-4138.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Phase distribution and corresponding piezoelectric responses in a morphotropic phase boundary Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystal revealed by confocal Raman spectroscopy and piezo-response force microscopy

AU - Hu, Qingyuan

AU - Alikin, D. O.

AU - Zelenovskiy, P. S.

AU - Ushakov, A. D.

AU - Chezganov, D. S.

AU - Bian, Jihong

AU - Zhao, Ye

AU - Tian, Ye

AU - Zhuang, Yongyong

AU - Li, Jinglei

AU - Jin, Li

AU - Xu, Zhuo

AU - Ya. Shur, Vladimir

AU - Wei, Xiaoyong

PY - 2019/11

Y1 - 2019/11

N2 - Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT) single crystals exhibit ultrahigh piezoelectric property and have already been applied in various industrial fields. Here, spatial distribution of coexistent phases and corresponding local piezoelectric responses in a morphotropic phase boundary (MPB) PMN-xPT single crystal are thoroughly investigated by confocal Raman spectroscopy coupled with piezo-response force microscopy (PFM). Different from previous studies on MPB crystals, spatial distribution of coexistent phases is exhibited intuitively in an image obtained by confocal Raman mapping. Via in-situ PFM measurements, domain morphology of each coexistent phase is observed. Moreover, local piezoelectric responses of each coexistent phase are obtained by switching spectroscopy PFM measurements, indicating that Ma and Mc phases behave like PNRs and polar matrix in PMN-xPT crystals Our work clarifies the contribution from different phases to the giant piezoelectric performance, which can deepen the understanding on the ultrahigh piezoelectricity in PMN-xPT crystals and provide the key point for developing novel high piezoelectricity materials.

AB - Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT) single crystals exhibit ultrahigh piezoelectric property and have already been applied in various industrial fields. Here, spatial distribution of coexistent phases and corresponding local piezoelectric responses in a morphotropic phase boundary (MPB) PMN-xPT single crystal are thoroughly investigated by confocal Raman spectroscopy coupled with piezo-response force microscopy (PFM). Different from previous studies on MPB crystals, spatial distribution of coexistent phases is exhibited intuitively in an image obtained by confocal Raman mapping. Via in-situ PFM measurements, domain morphology of each coexistent phase is observed. Moreover, local piezoelectric responses of each coexistent phase are obtained by switching spectroscopy PFM measurements, indicating that Ma and Mc phases behave like PNRs and polar matrix in PMN-xPT crystals Our work clarifies the contribution from different phases to the giant piezoelectric performance, which can deepen the understanding on the ultrahigh piezoelectricity in PMN-xPT crystals and provide the key point for developing novel high piezoelectricity materials.

KW - Confocal Raman spectroscopy

KW - Heterogeneous structure

KW - Local piezo-responses

KW - PFM

KW - Relaxor ferroelectric single crystal

UR - https://www.scopus.com/pages/publications/85066493353

U2 - 10.1016/j.jeurceramsoc.2019.05.046

DO - 10.1016/j.jeurceramsoc.2019.05.046

M3 - 文章

AN - SCOPUS:85066493353

SN - 0955-2219

VL - 39

SP - 4131

EP - 4138

JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

IS - 14

ER -

Hu Q, Alikin DO, Zelenovskiy PS, Ushakov AD, Chezganov DS, Bian J et al. Phase distribution and corresponding piezoelectric responses in a morphotropic phase boundary Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ single crystal revealed by confocal Raman spectroscopy and piezo-response force microscopy. Journal of the European Ceramic Society. 2019 Nov;39(14):4131-4138. doi: 10.1016/j.jeurceramsoc.2019.05.046