Perspective on interface engineering for capacitive energy storage polymer nanodielectrics

Polymer nanodielectrics with high breakdown strength (E_b), high energy density (U_e) and low energy loss have great potential to be used as capacitive energy storage materials of high-voltage film capacitors in modern electrical and electronic equipment, such as smart grids, new energy vehicles and pulse powered weapons. Usually, inorganic nanoparticles with high dielectric constant (ϵ_r) are added into a high E_b polymer matrix to achieve simultaneously enhanced ϵ_r and E_b, thus leading to nanodielectrics with high U_e. However, this strategy was seriously hampered by the uneven distribution of electric fields and inhomogeneous microstructures of the multi-phased nanodielectrics until increasing research work was focused on interface engineering. Recent progress in nanocomposites suggests that interface engineering plays a critical role in regulating the polarization and breakdown behaviors of the nanodielectrics, such as balancing ϵ_r and E_b, enhancing U_e and energy discharge efficiency (η). This article highlights the recent advances in the interface engineering of polymer nanodielectrics, including theoretical models, interface engineering strategies, and the latest characterization and fabrication techniques of high performance nanodielectrics. Finally, the challenges and opportunities in the interface engineering of the nanodielectrics in film capacitors are discussed and predicted from a practical point of view.