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One template approach to synthesize C-doped titania hollow spheres with high visible-light photocatalytic activity

  • Jian Wen Shi
  • , Jian Wei Chen
  • , Hao Jie Cui
  • , Ming Lai Fu
  • , Hong Yuan Luo
  • , Bin Xu
  • , Zhi Long Ye
  • Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Carbon-doped titania hollow spheres (THS) with unique hollow three-dimensional network structure were synthesized by a facile method using carbon spheres as template. The resultant samples, such as carbon spheres, carbon spheres coated with titania precursor, and final THS were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), energy dispersive X-ray spectrometer (EDS), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectra (FTIR), Brunauer-Emmett-Teller (BET) and UV-vis absorption spectrum. Based on the results of these characterizations, a reasonable formation mechanism of the hollow three-dimensional network structure was proposed. The photocatalytic activity of as-prepared THS was evaluated by decoloration of methylene blue solution under visible light irradiation. Results indicated that THS possessed higher visible light-induced photocatalytic activity than commercial P25, which could be attributed to its visible light absorption characteristic created by C-doping and the unique hollow three-dimensional network structure.

Original languageEnglish
Pages (from-to)226-232
Number of pages7
JournalChemical Engineering Journal
Volume195-196
DOIs
StatePublished - 1 Jul 2012
Externally publishedYes

Keywords

  • Carbon sphere
  • Hollow sphere
  • Photocatalysis
  • Titania

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