NNB-type tridentate boryl ligands enabling a highly active iridium catalyst for C–H borylation

Siyi Ding; Linghua Wang; Zongcheng Miao; Pengfei Li

doi:10.3390/molecules24071434

NNB-type tridentate boryl ligands enabling a highly active iridium catalyst for C–H borylation

Siyi Ding
, Linghua Wang
, Zongcheng Miao
, Pengfei Li

Frontier Institute of Science and Technology

Xijing University
Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Boryl ligands play a very important role in catalysis because of their very high electron-donating property. In this paper, NNB-type boryl anions were designed as tridentate ligands to promote aryl C–H borylation. In combination with [IrCl(COD)]₂, they generate a highly active catalyst for a broad range of (hetero)arene substrates, including highly electron-rich and/or sterically hindered ones. This work provides a new NNB-type tridentate boryl ligand to support homogeneous organometallic catalysis.

Original language	English
Article number	1434
Journal	Molecules
Volume	24
Issue number	7
DOIs	https://doi.org/10.3390/molecules24071434
State	Published - 11 Apr 2019

Keywords

Boryl ligand
C–H borylation reaction
Iridium-catalyzed

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title = "NNB-type tridentate boryl ligands enabling a highly active iridium catalyst for C–H borylation",

abstract = "Boryl ligands play a very important role in catalysis because of their very high electron-donating property. In this paper, NNB-type boryl anions were designed as tridentate ligands to promote aryl C–H borylation. In combination with [IrCl(COD)]2, they generate a highly active catalyst for a broad range of (hetero)arene substrates, including highly electron-rich and/or sterically hindered ones. This work provides a new NNB-type tridentate boryl ligand to support homogeneous organometallic catalysis.",

keywords = "Boryl ligand, C–H borylation reaction, Iridium-catalyzed",

author = "Siyi Ding and Linghua Wang and Zongcheng Miao and Pengfei Li",

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T1 - NNB-type tridentate boryl ligands enabling a highly active iridium catalyst for C–H borylation

AU - Ding, Siyi

AU - Wang, Linghua

AU - Miao, Zongcheng

AU - Li, Pengfei

PY - 2019/4/11

Y1 - 2019/4/11

N2 - Boryl ligands play a very important role in catalysis because of their very high electron-donating property. In this paper, NNB-type boryl anions were designed as tridentate ligands to promote aryl C–H borylation. In combination with [IrCl(COD)]2, they generate a highly active catalyst for a broad range of (hetero)arene substrates, including highly electron-rich and/or sterically hindered ones. This work provides a new NNB-type tridentate boryl ligand to support homogeneous organometallic catalysis.

AB - Boryl ligands play a very important role in catalysis because of their very high electron-donating property. In this paper, NNB-type boryl anions were designed as tridentate ligands to promote aryl C–H borylation. In combination with [IrCl(COD)]2, they generate a highly active catalyst for a broad range of (hetero)arene substrates, including highly electron-rich and/or sterically hindered ones. This work provides a new NNB-type tridentate boryl ligand to support homogeneous organometallic catalysis.

KW - Boryl ligand

KW - C–H borylation reaction

KW - Iridium-catalyzed

UR - https://www.scopus.com/pages/publications/85064590442

U2 - 10.3390/molecules24071434

DO - 10.3390/molecules24071434

M3 - 文章

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AN - SCOPUS:85064590442

SN - 1420-3049

VL - 24

JO - Molecules

JF - Molecules

IS - 7

M1 - 1434

ER -

NNB-type tridentate boryl ligands enabling a highly active iridium catalyst for C–H borylation

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Keywords

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