N,B-bidentate boryl ligand-supported iridium catalyst for efficient functional-group-directed C-H borylation

Guanghui Wang; Li Liu; Hong Wang; You Song Ding; Jing Zhou; Shuai Mao; Pengfei Li

doi:10.1021/jacs.6b11867

N,B-bidentate boryl ligand-supported iridium catalyst for efficient functional-group-directed C-H borylation

Guanghui Wang
, Li Liu
, Hong Wang
, You Song Ding
, Jing Zhou
, Shuai Mao
, Pengfei Li

Frontier Institute of Science and Technology

Xi'an Jiaotong University
Nankai University

Research output: Contribution to journal › Article › peer-review

147 Scopus citations

Abstract

Convenient silylborane precursors for introducing N,B-bidentate boryl ligands onto transition metals were designed, prepared, and employed in ready formation of irdium(IIl) complexes via Si-B oxidative addition. A practical, efficient catalytic ortho-borylation reaction of arenes with a broad range of directing groups was developed using an in situ generated catalyst from the silylborane preligand 3c and [IrCl(COD)]₂.

Original language	English
Pages (from-to)	91-94
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	139
Issue number	1
DOIs	https://doi.org/10.1021/jacs.6b11867
State	Published - 11 Jan 2017

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title = "N,B-bidentate boryl ligand-supported iridium catalyst for efficient functional-group-directed C-H borylation",

abstract = "Convenient silylborane precursors for introducing N,B-bidentate boryl ligands onto transition metals were designed, prepared, and employed in ready formation of irdium(IIl) complexes via Si-B oxidative addition. A practical, efficient catalytic ortho-borylation reaction of arenes with a broad range of directing groups was developed using an in situ generated catalyst from the silylborane preligand 3c and [IrCl(COD)]2.",

author = "Guanghui Wang and Li Liu and Hong Wang and Ding, \{You Song\} and Jing Zhou and Shuai Mao and Pengfei Li",

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T1 - N,B-bidentate boryl ligand-supported iridium catalyst for efficient functional-group-directed C-H borylation

AU - Wang, Guanghui

AU - Liu, Li

AU - Wang, Hong

AU - Ding, You Song

AU - Zhou, Jing

AU - Mao, Shuai

AU - Li, Pengfei

PY - 2017/1/11

Y1 - 2017/1/11

N2 - Convenient silylborane precursors for introducing N,B-bidentate boryl ligands onto transition metals were designed, prepared, and employed in ready formation of irdium(IIl) complexes via Si-B oxidative addition. A practical, efficient catalytic ortho-borylation reaction of arenes with a broad range of directing groups was developed using an in situ generated catalyst from the silylborane preligand 3c and [IrCl(COD)]2.

AB - Convenient silylborane precursors for introducing N,B-bidentate boryl ligands onto transition metals were designed, prepared, and employed in ready formation of irdium(IIl) complexes via Si-B oxidative addition. A practical, efficient catalytic ortho-borylation reaction of arenes with a broad range of directing groups was developed using an in situ generated catalyst from the silylborane preligand 3c and [IrCl(COD)]2.

UR - https://www.scopus.com/pages/publications/85019152820

U2 - 10.1021/jacs.6b11867

DO - 10.1021/jacs.6b11867

M3 - 文章

C2 - 27992177

AN - SCOPUS:85019152820

SN - 0002-7863

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SP - 91

EP - 94

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 1

ER -

N,B-bidentate boryl ligand-supported iridium catalyst for efficient functional-group-directed C-H borylation

Abstract

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