Molar ratio induced crystal transformation from coordination complex to coordination polymers

Peng Meng; Qian Cheng Luo; Aidan Brock; Xiaodong Wang; Mahboobeh Shahbazi; Aaron Micallef; John McMurtrie; Dongchen Qi; Yan Zhen Zheng; Jingsan Xu

doi:10.1016/j.cclet.2023.108542

Molar ratio induced crystal transformation from coordination complex to coordination polymers

Peng Meng
, Qian Cheng Luo
, Aidan Brock
, Xiaodong Wang
, Mahboobeh Shahbazi
, Aaron Micallef
, John McMurtrie
, Dongchen Qi
, Yan Zhen Zheng
, Jingsan Xu

School of Materials Science and Engineering

Queensland University of Technology
Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Coordination complex of a copper cyanurate (Cu(II)-CA) was transformed into coordination polymers upon the stimulus of extra Cu(II) through “directed Ostwald ripening”. By increasing the molar ratio of Cu(II) to CA, we obtained two coordination polymers with selective coordination sites: Cu(II)-κN(HCA)κN-Cu(II) and Cu(II)-κN(HCA)κO-Cu(II), which display disparate magnetic interactions.

Original language	English
Article number	108542
Journal	Chinese Chemical Letters
Volume	35
Issue number	4
DOIs	https://doi.org/10.1016/j.cclet.2023.108542
State	Published - Apr 2024

Keywords

Copper cyanurate
Molar ratio dependent crystal transformation
Molecular magnetism
One-dimensional chain
Ostwald ripening

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10.1016/j.cclet.2023.108542

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title = "Molar ratio induced crystal transformation from coordination complex to coordination polymers",

abstract = "Coordination complex of a copper cyanurate (Cu(II)-CA) was transformed into coordination polymers upon the stimulus of extra Cu(II) through “directed Ostwald ripening”. By increasing the molar ratio of Cu(II) to CA, we obtained two coordination polymers with selective coordination sites: Cu(II)-κN(HCA)κN-Cu(II) and Cu(II)-κN(HCA)κO-Cu(II), which display disparate magnetic interactions.",

keywords = "Copper cyanurate, Molar ratio dependent crystal transformation, Molecular magnetism, One-dimensional chain, Ostwald ripening",

author = "Peng Meng and Luo, \{Qian Cheng\} and Aidan Brock and Xiaodong Wang and Mahboobeh Shahbazi and Aaron Micallef and John McMurtrie and Dongchen Qi and Zheng, \{Yan Zhen\} and Jingsan Xu",

note = "Publisher Copyright: {\textcopyright} 2024",

year = "2024",

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doi = "10.1016/j.cclet.2023.108542",

language = "英语",

volume = "35",

journal = "Chinese Chemical Letters",

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TY - JOUR

T1 - Molar ratio induced crystal transformation from coordination complex to coordination polymers

AU - Meng, Peng

AU - Luo, Qian Cheng

AU - Brock, Aidan

AU - Wang, Xiaodong

AU - Shahbazi, Mahboobeh

AU - Micallef, Aaron

AU - McMurtrie, John

AU - Qi, Dongchen

AU - Zheng, Yan Zhen

AU - Xu, Jingsan

PY - 2024/4

Y1 - 2024/4

N2 - Coordination complex of a copper cyanurate (Cu(II)-CA) was transformed into coordination polymers upon the stimulus of extra Cu(II) through “directed Ostwald ripening”. By increasing the molar ratio of Cu(II) to CA, we obtained two coordination polymers with selective coordination sites: Cu(II)-κN(HCA)κN-Cu(II) and Cu(II)-κN(HCA)κO-Cu(II), which display disparate magnetic interactions.

AB - Coordination complex of a copper cyanurate (Cu(II)-CA) was transformed into coordination polymers upon the stimulus of extra Cu(II) through “directed Ostwald ripening”. By increasing the molar ratio of Cu(II) to CA, we obtained two coordination polymers with selective coordination sites: Cu(II)-κN(HCA)κN-Cu(II) and Cu(II)-κN(HCA)κO-Cu(II), which display disparate magnetic interactions.

KW - Copper cyanurate

KW - Molar ratio dependent crystal transformation

KW - Molecular magnetism

KW - One-dimensional chain

KW - Ostwald ripening

UR - https://www.scopus.com/pages/publications/85179072233

U2 - 10.1016/j.cclet.2023.108542

DO - 10.1016/j.cclet.2023.108542

M3 - 文章

AN - SCOPUS:85179072233

SN - 1001-8417

VL - 35

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 4

M1 - 108542

ER -

Molar ratio induced crystal transformation from coordination complex to coordination polymers

Abstract

Keywords

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