Modulated synthesis and isoreticular expansion of Th-MOFs with record high pore volume and surface area for iodine adsorption

  • Zi Jian Li
  • , Yu Ju
  • , Yu Ju
  • , Bowen Yu
  • , Xiaoling Wu
  • , Huangjie Lu
  • , Yongxin Li
  • , Jing Zhou
  • , Xiaofeng Guo
  • , Zhi Hui Zhang
  • , Jian Lin
  • , Jian Qiang Wang
  • , Jian Qiang Wang
  • , Shuao Wang

Research output: Contribution to journalArticlepeer-review

111 Scopus citations

Abstract

Modulated synthesis and isoreticular expansion of Th-MOFs enable the stepwise construction of hierarchical complexes in which porosity and functionality can be fine-tuned, affording new Th-MOFs with a record high void space (74.0%), the largest surface area (3396.5 m2 g-1) among thorium materials, and excellent adsorption capacities toward radioactive iodine.

Original languageEnglish
Pages (from-to)6715-6718
Number of pages4
JournalChemical Communications
Volume56
Issue number49
DOIs
StatePublished - 21 Jun 2020
Externally publishedYes

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