Modifying optical properties of ZnO nanowires via strain-gradient

  • Xue Wen Fu
  • , Qiang Fu
  • , Liang Zhi Kou
  • , Xin Li Zhu
  • , Rui Zhu
  • , Jun Xu
  • , Zhi Min Liao
  • , Qing Zhao
  • , Wan Lin Guo
  • , Da Peng Yu

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

We conduct systematical cathodoluminescence study on red-shift of near-band-edge emission energy in elastic bent ZnO nanowires with diameters within the exciton diffusion length (~ 200 nm) in liquid nitrogen temperature (81 K). By charactering the emission spectra of the nanowires with different local curvatures, we find a linear relationship between strain-gradient and the red-shift of near-band-edge emission photon energy, an elastic strain-gradient effect in semiconductor similar to the famous flexoelectric effect in liquid crystals. Our results provide a new route to understand the inhomogeneous strain effect on the energy bands and optical properties of semiconductors and should be useful for designing advanced nano-optoelectronic devices.

Original languageEnglish
Pages (from-to)509-515
Number of pages7
JournalFrontiers of Physics
Volume8
Issue number5
DOIs
StatePublished - Oct 2013
Externally publishedYes

Keywords

  • ZnO nanowire
  • cathodoluminescene
  • energy bands
  • exciton energy
  • strain-gradient

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