Missing small-bandgap metallofullerenes: Their isolation and electronic properties

Zhiyong Wang; Yusuke Nakanishi; Shoko Noda; Hiroyuki Niwa; Jinying Zhang; Ryo Kitaura; Hisanori Shinohara

doi:10.1002/anie.201305573

Missing small-bandgap metallofullerenes: Their isolation and electronic properties

Zhiyong Wang
, Yusuke Nakanishi
, Shoko Noda
, Hiroyuki Niwa
, Jinying Zhang
, Ryo Kitaura
, Hisanori Shinohara

Nagoya University

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Lost and found: In-situ exohedral trifluoromethylation of endohedral fullerenes using an arc-discharge method (see picture) gives access to a wide variety of missing unconventional metallofullerenes. Such otherwise insoluble and unstable metallofullerenes become soluble and stable in organic solvents after an exterior functionalization.

Original language	English
Pages (from-to)	11770-11774
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	45
DOIs	https://doi.org/10.1002/anie.201305573
State	Published - 4 Nov 2013
Externally published	Yes

Keywords

arc discharge
electronic structures
fullerenes
trifluoromethylation
yttrium

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10.1002/anie.201305573

Cite this

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abstract = "Lost and found: In-situ exohedral trifluoromethylation of endohedral fullerenes using an arc-discharge method (see picture) gives access to a wide variety of missing unconventional metallofullerenes. Such otherwise insoluble and unstable metallofullerenes become soluble and stable in organic solvents after an exterior functionalization.",

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T1 - Missing small-bandgap metallofullerenes

T2 - Their isolation and electronic properties

AU - Wang, Zhiyong

AU - Nakanishi, Yusuke

AU - Noda, Shoko

AU - Niwa, Hiroyuki

AU - Zhang, Jinying

AU - Kitaura, Ryo

AU - Shinohara, Hisanori

PY - 2013/11/4

Y1 - 2013/11/4

N2 - Lost and found: In-situ exohedral trifluoromethylation of endohedral fullerenes using an arc-discharge method (see picture) gives access to a wide variety of missing unconventional metallofullerenes. Such otherwise insoluble and unstable metallofullerenes become soluble and stable in organic solvents after an exterior functionalization.

AB - Lost and found: In-situ exohedral trifluoromethylation of endohedral fullerenes using an arc-discharge method (see picture) gives access to a wide variety of missing unconventional metallofullerenes. Such otherwise insoluble and unstable metallofullerenes become soluble and stable in organic solvents after an exterior functionalization.

KW - arc discharge

KW - electronic structures

KW - fullerenes

KW - trifluoromethylation

KW - yttrium

UR - https://www.scopus.com/pages/publications/84886791150

U2 - 10.1002/anie.201305573

DO - 10.1002/anie.201305573

M3 - 文章

AN - SCOPUS:84886791150

SN - 1433-7851

VL - 52

SP - 11770

EP - 11774

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 45

ER -

Missing small-bandgap metallofullerenes: Their isolation and electronic properties

Abstract

Keywords

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