Abstract
CaBaCo2O5+δ thin films were deposited on (001) LaAlO3 substrates by pulsed laser deposition. The microstructures of the film and substrate were studied by X-ray diffraction (XRD) and of transmission electron microscopy (TEM). Results show that (1) dislocations and twins appear in the LaAlO3 substrates, and the (100) wedge-shaped twin was the main type; (2) CaBaCo2O5+δ thin film was polycrystalline in nature, and the initial grain structure with a grain size of about 5-8 nm during growth was kept at the bottom of the film. While the grain size at the top of the film was larger, about 11-16 nm. Based on the observation results, a growth mechanism of the film was proposed. Possible processes to improve the film quality have also been discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 17050-17053 |
| Number of pages | 4 |
| Journal | Gongneng Cailiao/Journal of Functional Materials |
| Volume | 45 |
| Issue number | 17 |
| DOIs | |
| State | Published - 15 Sep 2014 |
| Externally published | Yes |
Keywords
- Growth mechanism
- Microstructure
- Polycrystalline thin films
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