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Microstructures and growth mechanisms of the polycrystalline CaBaCo2O5+δ thin films grown on (001) LaAlO3 substrates

  • Jun Chi Li
  • , Jiang Hua Chen
  • , Ying Ding
  • , Chun Rui Ma
  • , Chong Lin Chen
  • , Jing Yue Fang
  • , Xue Ao Zhang
  • Hunan University
  • University of Texas at San Antonio
  • National University of Defense Technology

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

CaBaCo2O5+δ thin films were deposited on (001) LaAlO3 substrates by pulsed laser deposition. The microstructures of the film and substrate were studied by X-ray diffraction (XRD) and of transmission electron microscopy (TEM). Results show that (1) dislocations and twins appear in the LaAlO3 substrates, and the (100) wedge-shaped twin was the main type; (2) CaBaCo2O5+δ thin film was polycrystalline in nature, and the initial grain structure with a grain size of about 5-8 nm during growth was kept at the bottom of the film. While the grain size at the top of the film was larger, about 11-16 nm. Based on the observation results, a growth mechanism of the film was proposed. Possible processes to improve the film quality have also been discussed.

Original languageEnglish
Pages (from-to)17050-17053
Number of pages4
JournalGongneng Cailiao/Journal of Functional Materials
Volume45
Issue number17
DOIs
StatePublished - 15 Sep 2014
Externally publishedYes

Keywords

  • Growth mechanism
  • Microstructure
  • Polycrystalline thin films

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