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Microstructural study on the stress corrosion cracking of alloy 690 in simulated pressurized water reactor primary environment

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4 Scopus citations

Abstract

This study was aimed at investigating the intergranular attack near a stress corrosion crack (SCC) of alloy 690 in simulated pressurized water reactor (PWR) primary water environment. Solution annealed alloy 690 was evaluated for its SCC initiation susceptibility in 360, °C hydrogenated pure water using slow strain rate tensile technique. After the test, a grain boundary showing SCC initiation was sampled with Focused Ion Beam (FIB) milling. The microstructure and elemental distribution near the crack tip were studied using transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM). The results show that intergranular oxidation occurs ahead of the crack tip and is preceded by diffusion induced grain boundary migration. The oxides at the crack tip are mainly composed of NiO and Cr2O3 which maintain rigid orientations with the neighboring grains. The adjacent migration zone is free of oxidization as a compact layer of Cr2O3 dominates at the oxide/substrate interfaces and the very tip region.

Original languageEnglish
Title of host publicationProceedings of the 18th International Conference on Environmental Degradation of Materials in Nuclear Power Systems – Water Reactors
EditorsDenise Paraventi, Michael Wright, John H. Jackson
PublisherSpringer International Publishing
Pages535-545
Number of pages11
ISBN (Print)9783319672434
DOIs
StatePublished - 2018
Externally publishedYes
Event18th International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors, 2017 - Portland, United States
Duration: 13 Aug 201717 Aug 2017

Publication series

NameMinerals, Metals and Materials Series
VolumePart F9
ISSN (Print)2367-1181
ISSN (Electronic)2367-1696

Conference

Conference18th International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors, 2017
Country/TerritoryUnited States
CityPortland
Period13/08/1717/08/17

Keywords

  • Alloy 690
  • Boundary migration
  • Intergranular oxidation
  • PWR
  • SCC

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