Magnetic-field dependence of nucleation undercoolings in non-magnetic metallic melts

The nucleation undercoolings of non-magnetic metals like paramagnetic aluminium in high magnetic fields were measured by the differential thermal analysis technique. It was shown that the nucleation undercooling of pure aluminium increased with increasing the magnetic field, while its melting temperature was hardly changed. Based on the model of magnetic dipoles at the interface, it is proposed that the magnetic-field-induced interfacial energy mainly contributes to the increase in undercooling. The change in undercooling in the magnetic field is calculated theoretically, which is in comparison with experimental data. Additionally, the inhibition of atom diffusion in the magnetic field plays a role in the change of undercooling.