Macroscopic supramolecular assembly of rigid building blocks through a flexible spacing coating

  • Mengjiao Cheng
  • , Feng Shi
  • , Jianshu Li
  • , Zaifu Lin
  • , Chao Jiang
  • , Meng Xiao
  • , Liqun Zhang
  • , Wantai Yang
  • , Toshio Nishi

Research output: Contribution to journalArticlepeer-review

108 Scopus citations

Abstract

Macroscopic supramolecular assembly is a promising method for manufacturing macroscopic, ordered structures for tissue-engineering scaffolds. A flexible spacing coating is shown to overcome undesired surface and size effects and to enable assembly of macroscopic cubes with host/guest groups. The assembled pairs disassembled upon introduction of competitive guest molecules, thereby demonstrating a multivalent assembly mechanism.

Original languageEnglish
Pages (from-to)3009-3013
Number of pages5
JournalAdvanced Materials
Volume26
Issue number19
DOIs
StatePublished - 21 May 2014
Externally publishedYes

Keywords

  • flexible spacing coating
  • macroscopic supramolecular assembly
  • multivalency
  • self-assembly
  • supramolecular assembly

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