Luminescence properties of Eu(III) complex/polyvinylpyrrolidone electrospun composite nanofibers

Xiaoping Zhang; Shipeng Wen; Shui Hu; Qi Chen; Hao Fong; Liqun Zhang; Li Liu

doi:10.1021/jp9119843

Luminescence properties of Eu(III) complex/polyvinylpyrrolidone electrospun composite nanofibers

Xiaoping Zhang
, Shipeng Wen
, Shui Hu
, Qi Chen
, Hao Fong
, Liqun Zhang
, Li Liu

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

Herein, we report that an innovative type of 1D nanomaterials, electrospun composite nanofibers (diameters ∼175 (±25 nm) containing a complex of Eu(TTA) ₃phen in a matrix of polyvinylpyrrolidone (PVP), was prepared and characterized, and their luminescent properties were evaluated. The study revealed that, when the content of Eu(TTA) ₃phen was low (i.e., less than 23 wt %), the Eu(TTA) ₃phen was predominantly distributed in the composite nanofibers as molecular clusters and/or nanoscaled particles with sizes smaller than 10 nm; this substantially enhanced intermolecular interactions between individual Eu(TTA) ₃phen molecules and the neighboring chain segments of PVP. The Judd-Ofelt theory was used to study the effect of the dispersion of Eu(TTA) ₃phen on the local chemical environment of Eu ³⁺ ions. The composite nanofibers demonstrated a significant improvement of luminescent efficiency compared with neat Eu(TTA) ₃phen.

Original language	English
Pages (from-to)	3898-3903
Number of pages	6
Journal	Journal of Physical Chemistry C
Volume	114
Issue number	9
DOIs	https://doi.org/10.1021/jp9119843
State	Published - 11 Mar 2010
Externally published	Yes

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title = "Luminescence properties of Eu(III) complex/polyvinylpyrrolidone electrospun composite nanofibers",

abstract = "Herein, we report that an innovative type of 1D nanomaterials, electrospun composite nanofibers (diameters ∼175 (±25 nm) containing a complex of Eu(TTA) 3phen in a matrix of polyvinylpyrrolidone (PVP), was prepared and characterized, and their luminescent properties were evaluated. The study revealed that, when the content of Eu(TTA) 3phen was low (i.e., less than 23 wt \%), the Eu(TTA) 3phen was predominantly distributed in the composite nanofibers as molecular clusters and/or nanoscaled particles with sizes smaller than 10 nm; this substantially enhanced intermolecular interactions between individual Eu(TTA) 3phen molecules and the neighboring chain segments of PVP. The Judd-Ofelt theory was used to study the effect of the dispersion of Eu(TTA) 3phen on the local chemical environment of Eu 3+ ions. The composite nanofibers demonstrated a significant improvement of luminescent efficiency compared with neat Eu(TTA) 3phen.",

author = "Xiaoping Zhang and Shipeng Wen and Shui Hu and Qi Chen and Hao Fong and Liqun Zhang and Li Liu",

year = "2010",

month = mar,

day = "11",

doi = "10.1021/jp9119843",

language = "英语",

volume = "114",

pages = "3898--3903",

journal = "Journal of Physical Chemistry C",

issn = "1932-7447",

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number = "9",

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TY - JOUR

T1 - Luminescence properties of Eu(III) complex/polyvinylpyrrolidone electrospun composite nanofibers

AU - Zhang, Xiaoping

AU - Wen, Shipeng

AU - Hu, Shui

AU - Chen, Qi

AU - Fong, Hao

AU - Zhang, Liqun

AU - Liu, Li

PY - 2010/3/11

Y1 - 2010/3/11

N2 - Herein, we report that an innovative type of 1D nanomaterials, electrospun composite nanofibers (diameters ∼175 (±25 nm) containing a complex of Eu(TTA) 3phen in a matrix of polyvinylpyrrolidone (PVP), was prepared and characterized, and their luminescent properties were evaluated. The study revealed that, when the content of Eu(TTA) 3phen was low (i.e., less than 23 wt %), the Eu(TTA) 3phen was predominantly distributed in the composite nanofibers as molecular clusters and/or nanoscaled particles with sizes smaller than 10 nm; this substantially enhanced intermolecular interactions between individual Eu(TTA) 3phen molecules and the neighboring chain segments of PVP. The Judd-Ofelt theory was used to study the effect of the dispersion of Eu(TTA) 3phen on the local chemical environment of Eu 3+ ions. The composite nanofibers demonstrated a significant improvement of luminescent efficiency compared with neat Eu(TTA) 3phen.

AB - Herein, we report that an innovative type of 1D nanomaterials, electrospun composite nanofibers (diameters ∼175 (±25 nm) containing a complex of Eu(TTA) 3phen in a matrix of polyvinylpyrrolidone (PVP), was prepared and characterized, and their luminescent properties were evaluated. The study revealed that, when the content of Eu(TTA) 3phen was low (i.e., less than 23 wt %), the Eu(TTA) 3phen was predominantly distributed in the composite nanofibers as molecular clusters and/or nanoscaled particles with sizes smaller than 10 nm; this substantially enhanced intermolecular interactions between individual Eu(TTA) 3phen molecules and the neighboring chain segments of PVP. The Judd-Ofelt theory was used to study the effect of the dispersion of Eu(TTA) 3phen on the local chemical environment of Eu 3+ ions. The composite nanofibers demonstrated a significant improvement of luminescent efficiency compared with neat Eu(TTA) 3phen.

UR - https://www.scopus.com/pages/publications/77949302750

U2 - 10.1021/jp9119843

DO - 10.1021/jp9119843

M3 - 文章

AN - SCOPUS:77949302750

SN - 1932-7447

VL - 114

SP - 3898

EP - 3903

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 9

ER -

Luminescence properties of Eu(III) complex/polyvinylpyrrolidone electrospun composite nanofibers

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