Local structure and controllable thermal expansion in the solid solution (Mn1-xNix)ZrF6

Fei Han; Lei Hu; Zhanning Liu; Qiang Li; Tao Wang; Yang Ren; Jinxia Deng; Jun Chen; Xianran Xing

doi:10.1039/c6qi00483k

Local structure and controllable thermal expansion in the solid solution (Mn_1-xNi_x)ZrF₆

Fei Han
, Lei Hu
, Zhanning Liu
, Qiang Li
, Tao Wang
, Yang Ren
, Jinxia Deng
, Jun Chen
, Xianran Xing

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

It is an interesting but challenge issue to prepare isotropic controllable thermal expansion materials with a wide coefficient of thermal expansion (CTE) range. Herein we report controllable thermal expansion in the double ReO₃-type (Mn_1-xNi_x)ZrF₆ solid solutions, whose CTE varies from -4.4 to +15.5 × 10^-6 K^-1 (300-700 K). In particular, zero thermal expansion has been obtained in the composition of (Mn_0.6Ni_0.4)ZrF₆. (Mn_1-xNi_x)ZrF₆ exhibits full solid solution character. The thermal expansion of (Mn_1-xNi_x)ZrF₆ is adjusted by the flexibility of the atomic linkages, which is confirmed by the technique of temperature-dependent high-energy synchrotron X-ray pair distribution function.

Original language	English
Pages (from-to)	343-347
Number of pages	5
Journal	Inorganic Chemistry Frontiers
Volume	4
Issue number	2
DOIs	https://doi.org/10.1039/c6qi00483k
State	Published - Feb 2017
Externally published	Yes

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title = "Local structure and controllable thermal expansion in the solid solution (Mn1-xNix)ZrF6 ",

abstract = "It is an interesting but challenge issue to prepare isotropic controllable thermal expansion materials with a wide coefficient of thermal expansion (CTE) range. Herein we report controllable thermal expansion in the double ReO3-type (Mn1-xNix)ZrF6 solid solutions, whose CTE varies from -4.4 to +15.5 × 10-6 K-1 (300-700 K). In particular, zero thermal expansion has been obtained in the composition of (Mn0.6Ni0.4)ZrF6. (Mn1-xNix)ZrF6 exhibits full solid solution character. The thermal expansion of (Mn1-xNix)ZrF6 is adjusted by the flexibility of the atomic linkages, which is confirmed by the technique of temperature-dependent high-energy synchrotron X-ray pair distribution function.",

author = "Fei Han and Lei Hu and Zhanning Liu and Qiang Li and Tao Wang and Yang Ren and Jinxia Deng and Jun Chen and Xianran Xing",

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T1 - Local structure and controllable thermal expansion in the solid solution (Mn1-xNix)ZrF6

AU - Han, Fei

AU - Hu, Lei

AU - Liu, Zhanning

AU - Li, Qiang

AU - Wang, Tao

AU - Ren, Yang

AU - Deng, Jinxia

AU - Chen, Jun

AU - Xing, Xianran

PY - 2017/2

Y1 - 2017/2

N2 - It is an interesting but challenge issue to prepare isotropic controllable thermal expansion materials with a wide coefficient of thermal expansion (CTE) range. Herein we report controllable thermal expansion in the double ReO3-type (Mn1-xNix)ZrF6 solid solutions, whose CTE varies from -4.4 to +15.5 × 10-6 K-1 (300-700 K). In particular, zero thermal expansion has been obtained in the composition of (Mn0.6Ni0.4)ZrF6. (Mn1-xNix)ZrF6 exhibits full solid solution character. The thermal expansion of (Mn1-xNix)ZrF6 is adjusted by the flexibility of the atomic linkages, which is confirmed by the technique of temperature-dependent high-energy synchrotron X-ray pair distribution function.

AB - It is an interesting but challenge issue to prepare isotropic controllable thermal expansion materials with a wide coefficient of thermal expansion (CTE) range. Herein we report controllable thermal expansion in the double ReO3-type (Mn1-xNix)ZrF6 solid solutions, whose CTE varies from -4.4 to +15.5 × 10-6 K-1 (300-700 K). In particular, zero thermal expansion has been obtained in the composition of (Mn0.6Ni0.4)ZrF6. (Mn1-xNix)ZrF6 exhibits full solid solution character. The thermal expansion of (Mn1-xNix)ZrF6 is adjusted by the flexibility of the atomic linkages, which is confirmed by the technique of temperature-dependent high-energy synchrotron X-ray pair distribution function.

UR - https://www.scopus.com/pages/publications/85013013346

U2 - 10.1039/c6qi00483k

DO - 10.1039/c6qi00483k

M3 - 文章

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SN - 2052-1553

VL - 4

SP - 343

EP - 347

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

IS - 2

ER -

Local structure and controllable thermal expansion in the solid solution (Mn_1-xNi_x)ZrF₆

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