Lithium-Ion Battery State-of-Charge Estimation Using Electrochemical Model with Sensitive Parameters Adjustment

State-of-charge (SOC) estimation of lithium-ion (Li-ion) batteries with good accuracy is of critical importance for battery management systems. For the model-based methods, the electrochemical model has been widely used due to its accuracy and ability to describe the internal behaviors of the battery. However, the uncertainty of parameters and the lack of correction from voltage also induce errors during long-time calculation. This paper proposes a particle filter (PF) based method to estimate Li-ion batteries’ SOC using electrochemical model, with sensitive parameter identification achieved using the particle swarm optimization (PSO) algorithm. First, a single particle model with electrolyte dynamics (SPME) is used in this work to reduce the computational burden of the battery electrochemical model, whose sensitive parameters are selected through the elementary effect test. Then, the representative sensitive parameters, which are difficult to measure directly, are adjusted by PSO for a high efficiency. Finally, a model-based SOC estimation framework is constructed with PF to achieve accurate Li-ion battery SOC. Compared with extended Kalman filter and equivalent circuit model, the proposed method shows high accuracy under three different driving cycles.