Liquid water transport and mechanical performance of electrospun gas diffusion layers

Self-humidification is becoming a popular strategy for water management in proton exchange membrane fuel cells (PEMFCs), owing to the advantages of decreased volume, cost, and parasitic power of the hydrogen fuel cell engine. Membrane dehydration is one of the key issues that seriously affect the performance and lifespan of PEMFCs under low humidity conditions. In this work, an electrospinning approach was employed to fabricate gas diffusion layers (e-GDLs) composed of nanosized carbon fibers with a nanoscale pore structure. Further, a vapor deposition of Dow Corning Sylgard 184 was utilized to apply a hydrophobic coating to enhance the hydrophobicity of the e-GDL. The fabricated e-GDL can help alleviate the dehydration of the catalyst-coated membrane by increasing the breakthrough pressure. The breakthrough pressure of the e-GDL is five folds higher than that of the current commercial GDL, owing to the combined effects of the nanostructure and enhanced hydrophobicity. This superior characteristic is expected to effectively alleviate membrane dehydration under low humidity conditions. In addition, the e-GDL has excellent elastic deformability, which can effectively alleviate the irreversible damage caused by the pre-tightening force in the stack assembly process, thus enhancing the durability and lifetime of PEMFCs.