Liquid-crystal engineering with anchor-shaped molecules: Honeycombs with hexagonal and trigonal symmetries formed by polyphilic bent-core molecules

  • Benjamin Glettner
  • , Feng Liu
  • , Xiangbing Zeng
  • , Marko Prehm
  • , Ute Baumeister
  • , Goran Ungar
  • , Carsten Tschierske

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

Anchored in hexagons: The molecules shown display two new complex liquid-crystalline phases formed by arrays of hexagonal cylinders, each hexagon comprising either three or six molecules. The phase type can be selected by choosing the right size ratio between the π-conjugated aromatic core (the anchor) and the flexible chain. One of the phases is the first columnar liquid crystal with trigonal symmetry. (Chemical Equation Presented).

Original languageEnglish
Pages (from-to)6080-6083
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number32
DOIs
StatePublished - 28 Jul 2008
Externally publishedYes

Keywords

  • Columnar phase
  • Liquid crystals
  • Nanostructures
  • Self-assembly
  • Structure elucidation

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