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Isothermal refolding in crystals of long alkanes in solution. II. Morphological changes accompanying thickening

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Abstract

The morphological changes accompanying isothermal thickening in C198H398 are studied by electron microscopy. The crystal morphologies confirm previous assertions that thickening occurs in a single step from once‐folded to extended chains and suggest solution‐mediated nucleation of the thickened crystal followed by rapid spreading via solid‐state diffusion.

Original languageEnglish
Pages (from-to)2365-2384
Number of pages20
JournalJournal of Polymer Science Part B: Polymer Physics
Volume28
Issue number12
DOIs
StatePublished - Nov 1990
Externally publishedYes

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