Iron-Catalyzed Thiolation and Selenylation of Cycloalkyl Hydroperoxides via C-C Bond Cleavage

Qing Xin Sun; He Chen; Shuai Liu; Xiao Qiang Wang; Xin Hua Duan; Li Na Guo

doi:10.1021/acs.joc.1c01366

Iron-Catalyzed Thiolation and Selenylation of Cycloalkyl Hydroperoxides via C-C Bond Cleavage

Qing Xin Sun
, He Chen
, Shuai Liu
, Xiao Qiang Wang
, Xin Hua Duan
, Li Na Guo

School of Chemistry

Xi'an Jiaotong University
Lanzhou University

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A cheap iron-catalyzed C-C bond cleavage/thiolation and selenylation of cycloalkyl hydroperoxides are presented. This redox-neutral protocol provides efficient access to diverse distal keto-functionalized thioethers and selenium compounds. Remarkably, only some amounts of disulfides are required for this transformation.

Original language	English
Pages (from-to)	11987-11997
Number of pages	11
Journal	Journal of Organic Chemistry
Volume	86
Issue number	17
DOIs	https://doi.org/10.1021/acs.joc.1c01366
State	Published - 3 Sep 2021

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title = "Iron-Catalyzed Thiolation and Selenylation of Cycloalkyl Hydroperoxides via C-C Bond Cleavage",

abstract = "A cheap iron-catalyzed C-C bond cleavage/thiolation and selenylation of cycloalkyl hydroperoxides are presented. This redox-neutral protocol provides efficient access to diverse distal keto-functionalized thioethers and selenium compounds. Remarkably, only some amounts of disulfides are required for this transformation.",

author = "Sun, \{Qing Xin\} and He Chen and Shuai Liu and Wang, \{Xiao Qiang\} and Duan, \{Xin Hua\} and Guo, \{Li Na\}",

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T1 - Iron-Catalyzed Thiolation and Selenylation of Cycloalkyl Hydroperoxides via C-C Bond Cleavage

AU - Sun, Qing Xin

AU - Chen, He

AU - Liu, Shuai

AU - Wang, Xiao Qiang

AU - Duan, Xin Hua

AU - Guo, Li Na

PY - 2021/9/3

Y1 - 2021/9/3

N2 - A cheap iron-catalyzed C-C bond cleavage/thiolation and selenylation of cycloalkyl hydroperoxides are presented. This redox-neutral protocol provides efficient access to diverse distal keto-functionalized thioethers and selenium compounds. Remarkably, only some amounts of disulfides are required for this transformation.

AB - A cheap iron-catalyzed C-C bond cleavage/thiolation and selenylation of cycloalkyl hydroperoxides are presented. This redox-neutral protocol provides efficient access to diverse distal keto-functionalized thioethers and selenium compounds. Remarkably, only some amounts of disulfides are required for this transformation.

UR - https://www.scopus.com/pages/publications/85114011402

U2 - 10.1021/acs.joc.1c01366

DO - 10.1021/acs.joc.1c01366

M3 - 文章

AN - SCOPUS:85114011402

SN - 0022-3263

VL - 86

SP - 11987

EP - 11997

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 17

ER -

Iron-Catalyzed Thiolation and Selenylation of Cycloalkyl Hydroperoxides via C-C Bond Cleavage

Abstract

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