Investigation of outer valence orbital of CF2Cl2 by a new type of electron momentum spectrometer

Chuan Gang Ning; Xue Guang Ren; Jing Kang Deng; Guo Lin Su; Shu Feng Zhang; Feng Huang; Gui Qin Li

doi:10.1088/1009-1963/14/12/016

Investigation of outer valence orbital of CF₂Cl₂ by a new type of electron momentum spectrometer

Chuan Gang Ning
, Xue Guang Ren
, Jing Kang Deng
, Guo Lin Su
, Shu Feng Zhang
, Feng Huang
, Gui Qin Li

Tsinghua University

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Electronic states of CF₂Cl₂ (dichlorodifluoromethane, Freon 12) have been studied using a new type of electron momentum spectrometer with a very high efficiency at an impact energy of 1200 eV plus binding energy. The experimental electron momentum profiles are compared with the density functional theory (DFT) and Hartree-Fock (HF) calculations. The relationship between orbital assignments in different coordinate systems is discussed. A new method of difference analysis based on the new type of electron momentum spectrometer is used to clarify the ambiguities regarding the orbital ordering.

Original language	English
Article number	016
Pages (from-to)	2467-2473
Number of pages	7
Journal	Chinese Physics
Volume	14
Issue number	12
DOIs	https://doi.org/10.1088/1009-1963/14/12/016
State	Published - 12 Dec 2005
Externally published	Yes

Keywords

CFCl
Electron momentum spectroscopy
Orbital assignment

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10.1088/1009-1963/14/12/016

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title = "Investigation of outer valence orbital of CF2Cl2 by a new type of electron momentum spectrometer",

abstract = "Electronic states of CF2Cl2 (dichlorodifluoromethane, Freon 12) have been studied using a new type of electron momentum spectrometer with a very high efficiency at an impact energy of 1200 eV plus binding energy. The experimental electron momentum profiles are compared with the density functional theory (DFT) and Hartree-Fock (HF) calculations. The relationship between orbital assignments in different coordinate systems is discussed. A new method of difference analysis based on the new type of electron momentum spectrometer is used to clarify the ambiguities regarding the orbital ordering.",

keywords = "CFCl, Electron momentum spectroscopy, Orbital assignment",

author = "Ning, \{Chuan Gang\} and Ren, \{Xue Guang\} and Deng, \{Jing Kang\} and Su, \{Guo Lin\} and Zhang, \{Shu Feng\} and Feng Huang and Li, \{Gui Qin\}",

year = "2005",

month = dec,

day = "12",

doi = "10.1088/1009-1963/14/12/016",

language = "英语",

volume = "14",

pages = "2467--2473",

journal = "Chinese Physics",

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number = "12",

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TY - JOUR

T1 - Investigation of outer valence orbital of CF2Cl2 by a new type of electron momentum spectrometer

AU - Ning, Chuan Gang

AU - Ren, Xue Guang

AU - Deng, Jing Kang

AU - Su, Guo Lin

AU - Zhang, Shu Feng

AU - Huang, Feng

AU - Li, Gui Qin

PY - 2005/12/12

Y1 - 2005/12/12

N2 - Electronic states of CF2Cl2 (dichlorodifluoromethane, Freon 12) have been studied using a new type of electron momentum spectrometer with a very high efficiency at an impact energy of 1200 eV plus binding energy. The experimental electron momentum profiles are compared with the density functional theory (DFT) and Hartree-Fock (HF) calculations. The relationship between orbital assignments in different coordinate systems is discussed. A new method of difference analysis based on the new type of electron momentum spectrometer is used to clarify the ambiguities regarding the orbital ordering.

AB - Electronic states of CF2Cl2 (dichlorodifluoromethane, Freon 12) have been studied using a new type of electron momentum spectrometer with a very high efficiency at an impact energy of 1200 eV plus binding energy. The experimental electron momentum profiles are compared with the density functional theory (DFT) and Hartree-Fock (HF) calculations. The relationship between orbital assignments in different coordinate systems is discussed. A new method of difference analysis based on the new type of electron momentum spectrometer is used to clarify the ambiguities regarding the orbital ordering.

KW - CFCl

KW - Electron momentum spectroscopy

KW - Orbital assignment

UR - https://www.scopus.com/pages/publications/28844491001

U2 - 10.1088/1009-1963/14/12/016

DO - 10.1088/1009-1963/14/12/016

M3 - 文章

AN - SCOPUS:28844491001

SN - 1009-1963

VL - 14

SP - 2467

EP - 2473

JO - Chinese Physics

JF - Chinese Physics

IS - 12

M1 - 016

ER -

Investigation of outer valence orbital of CF₂Cl₂ by a new type of electron momentum spectrometer

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Keywords

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