Industrial-grade rare-earth and perovskite oxide for high-performance electrolyte layer-free fuel cell

Chen Xia; Baoyuan Wang; Ying Ma; Yixiao Cai; Muhammad Afzal; Yanyan Liu; Yunjuan He; Wei Zhang; Wenjing Dong; Junjiao Li; Bin Zhu

doi:10.1016/j.jpowsour.2015.12.086

Industrial-grade rare-earth and perovskite oxide for high-performance electrolyte layer-free fuel cell

Chen Xia
, Baoyuan Wang
, Ying Ma
, Yixiao Cai
, Muhammad Afzal
, Yanyan Liu
, Yunjuan He
, Wei Zhang
, Wenjing Dong
, Junjiao Li
, Bin Zhu

Research output: Contribution to journal › Article › peer-review

101 Scopus citations

Abstract

In the present work, we report a composite of industrial-grade material LaCePr-oxide (LCP) and perovskite La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF) for advanced electrolyte layer-free fuel cells (EFFCs). The microstructure, morphology, and electrical properties of the LCP, LSCF, and LCP-LSCF composite were investigated and characterized by XRD, SEM, EDS, TEM, and EIS. Various ratios of LCP to LSCF in the composite were modulated to achieve balanced ionic and electronic conductivities. Fuel cell with an optimum ratio of 60 wt% LCP to 40 wt% LSCF reached the highest open circuit voltage (OCV) at 1.01 V and a maximum power density of 745 mW cm^-2 at 575°C, also displaying a good performance stability. The high performance is attributed to the interfacial mechanisms and electrode catalytic effects. The findings from the present study promote industrial-grade rare-earth oxide as a promising new material for innovative low temperature solid oxide fuel cell (LTSOFC) technology.

Original language	English
Pages (from-to)	270-279
Number of pages	10
Journal	Journal of Power Sources
Volume	307
DOIs	https://doi.org/10.1016/j.jpowsour.2015.12.086
State	Published - 1 Mar 2016
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Electrolyte layer-free fuel cell
Industrial-grade material
LaCePr-oxide (LCP)
LaSrCoFeO (LSCF)
Mixed conductor composite

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10.1016/j.jpowsour.2015.12.086

Cite this

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title = "Industrial-grade rare-earth and perovskite oxide for high-performance electrolyte layer-free fuel cell",

abstract = "In the present work, we report a composite of industrial-grade material LaCePr-oxide (LCP) and perovskite La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) for advanced electrolyte layer-free fuel cells (EFFCs). The microstructure, morphology, and electrical properties of the LCP, LSCF, and LCP-LSCF composite were investigated and characterized by XRD, SEM, EDS, TEM, and EIS. Various ratios of LCP to LSCF in the composite were modulated to achieve balanced ionic and electronic conductivities. Fuel cell with an optimum ratio of 60 wt\% LCP to 40 wt\% LSCF reached the highest open circuit voltage (OCV) at 1.01 V and a maximum power density of 745 mW cm-2 at 575°C, also displaying a good performance stability. The high performance is attributed to the interfacial mechanisms and electrode catalytic effects. The findings from the present study promote industrial-grade rare-earth oxide as a promising new material for innovative low temperature solid oxide fuel cell (LTSOFC) technology.",

keywords = "Electrolyte layer-free fuel cell, Industrial-grade material, LaCePr-oxide (LCP), LaSrCoFeO (LSCF), Mixed conductor composite",

author = "Chen Xia and Baoyuan Wang and Ying Ma and Yixiao Cai and Muhammad Afzal and Yanyan Liu and Yunjuan He and Wei Zhang and Wenjing Dong and Junjiao Li and Bin Zhu",

year = "2016",

month = mar,

day = "1",

doi = "10.1016/j.jpowsour.2015.12.086",

language = "英语",

volume = "307",

pages = "270--279",

journal = "Journal of Power Sources",

issn = "0378-7753",

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}

TY - JOUR

T1 - Industrial-grade rare-earth and perovskite oxide for high-performance electrolyte layer-free fuel cell

AU - Xia, Chen

AU - Wang, Baoyuan

AU - Ma, Ying

AU - Cai, Yixiao

AU - Afzal, Muhammad

AU - Liu, Yanyan

AU - He, Yunjuan

AU - Zhang, Wei

AU - Dong, Wenjing

AU - Li, Junjiao

AU - Zhu, Bin

PY - 2016/3/1

Y1 - 2016/3/1

N2 - In the present work, we report a composite of industrial-grade material LaCePr-oxide (LCP) and perovskite La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) for advanced electrolyte layer-free fuel cells (EFFCs). The microstructure, morphology, and electrical properties of the LCP, LSCF, and LCP-LSCF composite were investigated and characterized by XRD, SEM, EDS, TEM, and EIS. Various ratios of LCP to LSCF in the composite were modulated to achieve balanced ionic and electronic conductivities. Fuel cell with an optimum ratio of 60 wt% LCP to 40 wt% LSCF reached the highest open circuit voltage (OCV) at 1.01 V and a maximum power density of 745 mW cm-2 at 575°C, also displaying a good performance stability. The high performance is attributed to the interfacial mechanisms and electrode catalytic effects. The findings from the present study promote industrial-grade rare-earth oxide as a promising new material for innovative low temperature solid oxide fuel cell (LTSOFC) technology.

AB - In the present work, we report a composite of industrial-grade material LaCePr-oxide (LCP) and perovskite La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) for advanced electrolyte layer-free fuel cells (EFFCs). The microstructure, morphology, and electrical properties of the LCP, LSCF, and LCP-LSCF composite were investigated and characterized by XRD, SEM, EDS, TEM, and EIS. Various ratios of LCP to LSCF in the composite were modulated to achieve balanced ionic and electronic conductivities. Fuel cell with an optimum ratio of 60 wt% LCP to 40 wt% LSCF reached the highest open circuit voltage (OCV) at 1.01 V and a maximum power density of 745 mW cm-2 at 575°C, also displaying a good performance stability. The high performance is attributed to the interfacial mechanisms and electrode catalytic effects. The findings from the present study promote industrial-grade rare-earth oxide as a promising new material for innovative low temperature solid oxide fuel cell (LTSOFC) technology.

KW - Electrolyte layer-free fuel cell

KW - Industrial-grade material

KW - LaCePr-oxide (LCP)

KW - LaSrCoFeO (LSCF)

KW - Mixed conductor composite

UR - https://www.scopus.com/pages/publications/84953923409

U2 - 10.1016/j.jpowsour.2015.12.086

DO - 10.1016/j.jpowsour.2015.12.086

M3 - 文章

AN - SCOPUS:84953923409

SN - 0378-7753

VL - 307

SP - 270

EP - 279

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -

Industrial-grade rare-earth and perovskite oxide for high-performance electrolyte layer-free fuel cell

Abstract

UN SDGs

Keywords

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