Incorporation of neptunium(VI) into a uranyl selenite

Nathan A. Meredith; Matthew J. Polinski; Jian Lin; Antonio Simonetti; Thomas E. Albrecht-Schmitt

doi:10.1021/ic301682b

Incorporation of neptunium(VI) into a uranyl selenite

Nathan A. Meredith
, Matthew J. Polinski
, Jian Lin
, Antonio Simonetti
, Thomas E. Albrecht-Schmitt

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The incorporation of neptunium(VI) into the layered uranyl selenite Cs[(UO ₂)(HSeO ₃)(SeO ₃)] has yielded the highest level of neptunium uptake in a uranyl compound to date with an average of 12(±3)% substitution of Np ^VI for U ^VI. Furthermore, this is the first case in nearly 2 decades of dedicated incorporation studies in which the oxidation state of neptunium has been determined spectroscopically in a doped uranyl compound and also the first time in which neptunium incorporation has resulted in a structural transformation.

Original language	English
Pages (from-to)	10480-10482
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	20
DOIs	https://doi.org/10.1021/ic301682b
State	Published - 15 Oct 2012
Externally published	Yes

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title = "Incorporation of neptunium(VI) into a uranyl selenite",

abstract = "The incorporation of neptunium(VI) into the layered uranyl selenite Cs[(UO 2)(HSeO 3)(SeO 3)] has yielded the highest level of neptunium uptake in a uranyl compound to date with an average of 12(±3)\% substitution of Np VI for U VI. Furthermore, this is the first case in nearly 2 decades of dedicated incorporation studies in which the oxidation state of neptunium has been determined spectroscopically in a doped uranyl compound and also the first time in which neptunium incorporation has resulted in a structural transformation.",

author = "Meredith, \{Nathan A.\} and Polinski, \{Matthew J.\} and Jian Lin and Antonio Simonetti and Albrecht-Schmitt, \{Thomas E.\}",

year = "2012",

month = oct,

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doi = "10.1021/ic301682b",

language = "英语",

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journal = "Inorganic Chemistry",

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T1 - Incorporation of neptunium(VI) into a uranyl selenite

AU - Meredith, Nathan A.

AU - Polinski, Matthew J.

AU - Lin, Jian

AU - Simonetti, Antonio

AU - Albrecht-Schmitt, Thomas E.

PY - 2012/10/15

Y1 - 2012/10/15

N2 - The incorporation of neptunium(VI) into the layered uranyl selenite Cs[(UO 2)(HSeO 3)(SeO 3)] has yielded the highest level of neptunium uptake in a uranyl compound to date with an average of 12(±3)% substitution of Np VI for U VI. Furthermore, this is the first case in nearly 2 decades of dedicated incorporation studies in which the oxidation state of neptunium has been determined spectroscopically in a doped uranyl compound and also the first time in which neptunium incorporation has resulted in a structural transformation.

AB - The incorporation of neptunium(VI) into the layered uranyl selenite Cs[(UO 2)(HSeO 3)(SeO 3)] has yielded the highest level of neptunium uptake in a uranyl compound to date with an average of 12(±3)% substitution of Np VI for U VI. Furthermore, this is the first case in nearly 2 decades of dedicated incorporation studies in which the oxidation state of neptunium has been determined spectroscopically in a doped uranyl compound and also the first time in which neptunium incorporation has resulted in a structural transformation.

UR - https://www.scopus.com/pages/publications/84867544495

U2 - 10.1021/ic301682b

DO - 10.1021/ic301682b

M3 - 文章

AN - SCOPUS:84867544495

SN - 0020-1669

VL - 51

SP - 10480

EP - 10482

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 20

ER -

Incorporation of neptunium(VI) into a uranyl selenite

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