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Hot spots engineering in hierarchical silver nanocap array for surface-enhanced Raman scattering

  • Jun Wang
  • , Liqing Huang
  • , Lipeng Zhai
  • , Lin Yuan
  • , Lihua Zhao
  • , Weiwei Zhang
  • , Dongzhi Shan
  • , Aiwen Hao
  • , Xuehong Feng
  • , Jian Zhu
  • Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

We proposed a rapid, simple and room-temperature method to fabricate hierarchical silver nanocap arrays, in which hot spots could be facilely engineered on three-dimensional curved surface. Both optical property and surface-enhanced Raman scattering (SERS) activity displayed non-monotonic Ag thickness dependence. Furthermore, the simulation results obtained by finite-difference time-domain (FDTD) method reveal that hot spots intensity and density on three-dimensional curved surface significantly vary and strongly depend on deposited Ag thickness. The investigation opens a possibility for facile fabrication of SERS substrate with promising hot spot engineering on three-dimensional surface and extremely high SERS activity.

Original languageEnglish
Pages (from-to)605-609
Number of pages5
JournalApplied Surface Science
Volume261
DOIs
StatePublished - 15 Nov 2012

Keywords

  • Finite-difference time-domain (FDTD)
  • Hard anodization (HA)
  • Hot spots
  • Nanocap arrays
  • Surface-enhanced Raman scattering (SERS)

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