Highly regioselective synthesis of 2,3-disubstituted indenes via a novel palladium-catalyzed cyclization reaction of propargylic carbonates with carbon nucleophiles

Xin Hua Duan; Li Na Guo; Hai Peng Bi; Xue Yuan Liu; Yong Min Liang

doi:10.1021/ol062405f

Highly regioselective synthesis of 2,3-disubstituted indenes via a novel palladium-catalyzed cyclization reaction of propargylic carbonates with carbon nucleophiles

Xin Hua Duan
, Li Na Guo
, Hai Peng Bi
, Xue Yuan Liu
, Yong Min Liang

Lanzhou University
CAS - Lanzhou Institute of Chemical Physics

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

(Diagram presented) Palladium-catalyzed reaction of propargylic carbonates with carbon nucleophiles offers an efficient, direct route to highly substituted indenes. The reaction conditions and the scope of the process are examined, and a possible mechanism is proposed.

Original language	English
Pages (from-to)	5777-5780
Number of pages	4
Journal	Organic Letters
Volume	8
Issue number	25
DOIs	https://doi.org/10.1021/ol062405f
State	Published - 7 Dec 2006
Externally published	Yes

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10.1021/ol062405f

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@article{d52b7427402641cfbb955bb3f4350996,

title = "Highly regioselective synthesis of 2,3-disubstituted indenes via a novel palladium-catalyzed cyclization reaction of propargylic carbonates with carbon nucleophiles",

abstract = "(Diagram presented) Palladium-catalyzed reaction of propargylic carbonates with carbon nucleophiles offers an efficient, direct route to highly substituted indenes. The reaction conditions and the scope of the process are examined, and a possible mechanism is proposed.",

author = "Duan, \{Xin Hua\} and Guo, \{Li Na\} and Bi, \{Hai Peng\} and Liu, \{Xue Yuan\} and Liang, \{Yong Min\}",

year = "2006",

month = dec,

day = "7",

doi = "10.1021/ol062405f",

language = "英语",

volume = "8",

pages = "5777--5780",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "25",

}

TY - JOUR

T1 - Highly regioselective synthesis of 2,3-disubstituted indenes via a novel palladium-catalyzed cyclization reaction of propargylic carbonates with carbon nucleophiles

AU - Duan, Xin Hua

AU - Guo, Li Na

AU - Bi, Hai Peng

AU - Liu, Xue Yuan

AU - Liang, Yong Min

PY - 2006/12/7

Y1 - 2006/12/7

N2 - (Diagram presented) Palladium-catalyzed reaction of propargylic carbonates with carbon nucleophiles offers an efficient, direct route to highly substituted indenes. The reaction conditions and the scope of the process are examined, and a possible mechanism is proposed.

AB - (Diagram presented) Palladium-catalyzed reaction of propargylic carbonates with carbon nucleophiles offers an efficient, direct route to highly substituted indenes. The reaction conditions and the scope of the process are examined, and a possible mechanism is proposed.

UR - https://www.scopus.com/pages/publications/33846287946

U2 - 10.1021/ol062405f

DO - 10.1021/ol062405f

M3 - 文章

AN - SCOPUS:33846287946

SN - 1523-7060

VL - 8

SP - 5777

EP - 5780

JO - Organic Letters

JF - Organic Letters

IS - 25

ER -

Highly regioselective synthesis of 2,3-disubstituted indenes via a novel palladium-catalyzed cyclization reaction of propargylic carbonates with carbon nucleophiles

Abstract

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