High-Performance Lead-Free Solar Cells Based on Tin-Halide Perovskite Thin Films Functionalized by a Divalent Organic Cation

Min Chen; Qingshun Dong; Felix T. Eickemeyer; Yuhang Liu; Zhenghong Dai; Alexander D. Carl; Behzad Bahrami; Ashraful H. Chowdhury; Ronald L. Grimm; Yantao Shi; Qiquan Qiao; Shaik Mohammed Zakeeruddin; Michael Grätzel; Nitin P. Padture

doi:10.1021/acsenergylett.0c00888

High-Performance Lead-Free Solar Cells Based on Tin-Halide Perovskite Thin Films Functionalized by a Divalent Organic Cation

Min Chen
, Qingshun Dong
, Felix T. Eickemeyer
, Yuhang Liu
, Zhenghong Dai
, Alexander D. Carl
, Behzad Bahrami
, Ashraful H. Chowdhury
, Ronald L. Grimm
, Yantao Shi
, Qiquan Qiao
, Shaik Mohammed Zakeeruddin
, Michael Grätzel
, Nitin P. Padture

Brown University
Dalian University of Technology
Swiss Federal Institute of Technology Lausanne
Worcester Polytechnic Institute
South Dakota State University

Research output: Contribution to journal › Article › peer-review

111 Scopus citations

Abstract

Tin-based halide perovskite solar cells (PSCs) hold the most promise among lead-free PSCs, but they are plagued with inadequate environmental stability and power-conversion efficiency (PCE). Here we demonstrate that the optimum incorporation of a bulky divalent organic cation, 4-(aminomethyl)piperidinium (4AMP), in FASnI3 thin films improves stability, optoelectronic properties, and PSC performance. The optimized PSC yields a maximum PCE of 10.9% and good 500-h operational stability under continuous illumination. This is attributed to the unique thin-film structure, where the strong ionic bonding afforded by divalent 4AMP may provide near-full-coverage functionalization (encapsulation) of FASnI3 grain surfaces and grain boundaries, retarding O2/H2O ingression and mitigating Sn-defects for reduced photocarrier nonradiative recombination.

Original language	English
Pages (from-to)	2223-2230
Number of pages	8
Journal	ACS Energy Letters
Volume	5
Issue number	7
DOIs	https://doi.org/10.1021/acsenergylett.0c00888
State	Published - 10 Jul 2020
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Access to Document

10.1021/acsenergylett.0c00888

Cite this

Chen, M., Dong, Q., Eickemeyer, F. T., Liu, Y., Dai, Z., Carl, A. D., Bahrami, B., Chowdhury, A. H., Grimm, R. L., Shi, Y., Qiao, Q., Zakeeruddin, S. M., Grätzel, M., & Padture, N. P. (2020). High-Performance Lead-Free Solar Cells Based on Tin-Halide Perovskite Thin Films Functionalized by a Divalent Organic Cation. ACS Energy Letters, 5(7), 2223-2230. https://doi.org/10.1021/acsenergylett.0c00888

@article{fe6958e19bdb426cbdc9de95ff14e0ca,

title = "High-Performance Lead-Free Solar Cells Based on Tin-Halide Perovskite Thin Films Functionalized by a Divalent Organic Cation",

abstract = "Tin-based halide perovskite solar cells (PSCs) hold the most promise among lead-free PSCs, but they are plagued with inadequate environmental stability and power-conversion efficiency (PCE). Here we demonstrate that the optimum incorporation of a bulky divalent organic cation, 4-(aminomethyl)piperidinium (4AMP), in FASnI3 thin films improves stability, optoelectronic properties, and PSC performance. The optimized PSC yields a maximum PCE of 10.9\% and good 500-h operational stability under continuous illumination. This is attributed to the unique thin-film structure, where the strong ionic bonding afforded by divalent 4AMP may provide near-full-coverage functionalization (encapsulation) of FASnI3 grain surfaces and grain boundaries, retarding O2/H2O ingression and mitigating Sn-defects for reduced photocarrier nonradiative recombination.",

author = "Min Chen and Qingshun Dong and Eickemeyer, \{Felix T.\} and Yuhang Liu and Zhenghong Dai and Carl, \{Alexander D.\} and Behzad Bahrami and Chowdhury, \{Ashraful H.\} and Grimm, \{Ronald L.\} and Yantao Shi and Qiquan Qiao and Zakeeruddin, \{Shaik Mohammed\} and Michael Gr{\"a}tzel and Padture, \{Nitin P.\}",

note = "Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",

year = "2020",

month = jul,

day = "10",

doi = "10.1021/acsenergylett.0c00888",

language = "英语",

volume = "5",

pages = "2223--2230",

journal = "ACS Energy Letters",

issn = "2380-8195",

publisher = "American Chemical Society",

number = "7",

}

Chen, M, Dong, Q, Eickemeyer, FT, Liu, Y, Dai, Z, Carl, AD, Bahrami, B, Chowdhury, AH, Grimm, RL, Shi, Y, Qiao, Q, Zakeeruddin, SM, Grätzel, M & Padture, NP 2020, 'High-Performance Lead-Free Solar Cells Based on Tin-Halide Perovskite Thin Films Functionalized by a Divalent Organic Cation', ACS Energy Letters, vol. 5, no. 7, pp. 2223-2230. https://doi.org/10.1021/acsenergylett.0c00888

TY - JOUR

T1 - High-Performance Lead-Free Solar Cells Based on Tin-Halide Perovskite Thin Films Functionalized by a Divalent Organic Cation

AU - Chen, Min

AU - Dong, Qingshun

AU - Eickemeyer, Felix T.

AU - Liu, Yuhang

AU - Dai, Zhenghong

AU - Carl, Alexander D.

AU - Bahrami, Behzad

AU - Chowdhury, Ashraful H.

AU - Grimm, Ronald L.

AU - Shi, Yantao

AU - Qiao, Qiquan

AU - Zakeeruddin, Shaik Mohammed

AU - Grätzel, Michael

AU - Padture, Nitin P.

PY - 2020/7/10

Y1 - 2020/7/10

N2 - Tin-based halide perovskite solar cells (PSCs) hold the most promise among lead-free PSCs, but they are plagued with inadequate environmental stability and power-conversion efficiency (PCE). Here we demonstrate that the optimum incorporation of a bulky divalent organic cation, 4-(aminomethyl)piperidinium (4AMP), in FASnI3 thin films improves stability, optoelectronic properties, and PSC performance. The optimized PSC yields a maximum PCE of 10.9% and good 500-h operational stability under continuous illumination. This is attributed to the unique thin-film structure, where the strong ionic bonding afforded by divalent 4AMP may provide near-full-coverage functionalization (encapsulation) of FASnI3 grain surfaces and grain boundaries, retarding O2/H2O ingression and mitigating Sn-defects for reduced photocarrier nonradiative recombination.

AB - Tin-based halide perovskite solar cells (PSCs) hold the most promise among lead-free PSCs, but they are plagued with inadequate environmental stability and power-conversion efficiency (PCE). Here we demonstrate that the optimum incorporation of a bulky divalent organic cation, 4-(aminomethyl)piperidinium (4AMP), in FASnI3 thin films improves stability, optoelectronic properties, and PSC performance. The optimized PSC yields a maximum PCE of 10.9% and good 500-h operational stability under continuous illumination. This is attributed to the unique thin-film structure, where the strong ionic bonding afforded by divalent 4AMP may provide near-full-coverage functionalization (encapsulation) of FASnI3 grain surfaces and grain boundaries, retarding O2/H2O ingression and mitigating Sn-defects for reduced photocarrier nonradiative recombination.

UR - https://www.scopus.com/pages/publications/85089532868

U2 - 10.1021/acsenergylett.0c00888

DO - 10.1021/acsenergylett.0c00888

M3 - 文章

AN - SCOPUS:85089532868

SN - 2380-8195

VL - 5

SP - 2223

EP - 2230

JO - ACS Energy Letters

JF - ACS Energy Letters

IS - 7

ER -

High-Performance Lead-Free Solar Cells Based on Tin-Halide Perovskite Thin Films Functionalized by a Divalent Organic Cation

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this