TY - JOUR
T1 - High electrostrictive coefficient Q33in lead-free Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 piezoelectric ceramics
AU - Li, Fei
AU - Jin, Li
AU - Guo, Runping
N1 - Publisher Copyright:
© 2014 AIP Publishing LLC.
PY - 2014/12/8
Y1 - 2014/12/8
N2 - In this study, the electrostrictive effect in Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca 0.3)TiO3 (BZT-xBCT, x = 0.4, 0.5, and 0.6) ceramics was investigated to gain understanding of their high piezoelectric activity. The electrostrictive coefficient Q33 of the BZT-xBCT ceramics was observed to be around 0.04 m4/C2, twice that reported for Pb(Zr,Ti)O3-based ceramics. The Q33 was found to be quite stable with respect to temperature and composition for the BZT-xBCT ceramics. The addition of Fe3+ dopant to the ceramics greatly decreased their Curie temperature without affecting their Q33, which remained 0.04 m4/C2. Moreover, a high and hysteresis-free electric-field-induced strain was obtained for 2 at. % Fe-doped BZT-0.5BCT ceramics at room temperature, caused by their high Q33 coefficient and lower-than-room-temperature Curie temperature. The small-signal M33 coefficient of 2 at. % Fe-doped BZT-0.5BCT ceramics was found to be 1.5 × 10-16 m2/V2 (0.32 × 10-16 m2/V2 for undoped counterpart). These results indicate that 2 at. % Fe-doped BZT-0.5BCT ceramics have great potential as alternatives for hard Pb(Zr,Ti)O3 ceramics in actuator applications, where reproducible and non-hysteretic deformation responses are required.
AB - In this study, the electrostrictive effect in Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca 0.3)TiO3 (BZT-xBCT, x = 0.4, 0.5, and 0.6) ceramics was investigated to gain understanding of their high piezoelectric activity. The electrostrictive coefficient Q33 of the BZT-xBCT ceramics was observed to be around 0.04 m4/C2, twice that reported for Pb(Zr,Ti)O3-based ceramics. The Q33 was found to be quite stable with respect to temperature and composition for the BZT-xBCT ceramics. The addition of Fe3+ dopant to the ceramics greatly decreased their Curie temperature without affecting their Q33, which remained 0.04 m4/C2. Moreover, a high and hysteresis-free electric-field-induced strain was obtained for 2 at. % Fe-doped BZT-0.5BCT ceramics at room temperature, caused by their high Q33 coefficient and lower-than-room-temperature Curie temperature. The small-signal M33 coefficient of 2 at. % Fe-doped BZT-0.5BCT ceramics was found to be 1.5 × 10-16 m2/V2 (0.32 × 10-16 m2/V2 for undoped counterpart). These results indicate that 2 at. % Fe-doped BZT-0.5BCT ceramics have great potential as alternatives for hard Pb(Zr,Ti)O3 ceramics in actuator applications, where reproducible and non-hysteretic deformation responses are required.
UR - https://www.scopus.com/pages/publications/84915750457
U2 - 10.1063/1.4904019
DO - 10.1063/1.4904019
M3 - 文章
AN - SCOPUS:84915750457
SN - 0003-6951
VL - 105
JO - Applied Physics Letters
JF - Applied Physics Letters
IS - 23
M1 - 232903
ER -